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CS-W001157 4
Total: USD 88.00

Diallyl carbonate

  • CAS No. 15022-08-9

  • Cat. No. CS-0204418
  • Purity≥98%
  • MDL No.MFCD00008645

*For research and further manufacturing use only, not for direct human use.

Diallyl carbonate|CS-0204418

Structure of 15022-08-9

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General Information

  • CAS No. 15022-08-9
  • Cat. No. CS-0204418
  • Purity ≥98%
  • MDL No. MFCD00008645
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₁₀O₃
  • Molecular Weight 142.15
  • Synonym(s) carbonicacid,di-2-propenylester
  • SMILES O=C(OCC=C)OCC=C

Description

Diallyl carbonate is an acrylating agent. Allyl carbonates are widely employed in Tsuji-Trost allylation, generating carbanion, boronate, phosphide, amide and alkoxide, nucleophiles in situ and improving reaction rates over allyl acetate. Allyl carbonates are also of considerable interest for the intramolecular decarboxylative assymetric couplings.Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh3), generates glycerol carbonate.

Synthesis

  • Route1
    • null|null
      124-38-9
    • null|null
      107-18-6
    • ~57%
    • In-stock
      Diallyl carbonate|CS-0204418
      15022-08-9

    References

    • Yamazaki, Yusuke; Kakuma, Kasumi; Du, Ya; Saito, Susumu Tetrahedron, 2010 , vol. 66, # 51 p. 9675 - 9680
  • Route2
    • null|null
      107-18-6
    • null|null
      616-38-6
    • ~94%
    • In-stock
      Diallyl carbonate|CS-0204418
      15022-08-9

    References

    • Mutlu, Hatice; Ruiz, Johal; Solleder, Susanne C.; Meier, Michael A. R. Green Chemistry, 2012 , vol. 14, # 6 p. 1728 - 1735
  • Route3
    • null|null
      107-18-6
    • null|null
      503-38-8
    • ~85%
    • In-stock
      Diallyl carbonate|CS-0204418
      15022-08-9

    References

    • Tsuji, Jiro; Shimizu, Isao; Minami, Ichiro; Ohashi, Yukihiro; Sugiura, Teruo; Takahashi, Kazuhiko Journal of Organic Chemistry, 1985 , vol. 50, # 9 p. 1523 - 1529

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Warning
UN#: 3272
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226-H315-H319-H335
Precautionary Statements : P210-P233-P240-P241-P242-P243-P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   35.53
  • LogP   1.5116
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   4

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