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CS-W001157 4
Total: USD 88.00

Ally methyl carbonate,98% (stabilized with MEHQ)

  • CAS No. 35466-83-2

  • Cat. No. CS-0040098
  • Purity98% (stabilized with MEHQ)
  • MDL No.MFCD00134545

*For research and further manufacturing use only, not for direct human use.

Ally methyl carbonate,98% (stabilized with MEHQ)|CS-0040098

Structure of 35466-83-2

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General Information

  • CAS No. 35466-83-2
  • Cat. No. CS-0040098
  • Purity 98% (stabilized with MEHQ)
  • MDL No. MFCD00134545
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅H₈O₃
  • Molecular Weight 116.12
  • Synonym(s) methyl prop-2-en-1-yl carbonate
  • SMILES O=C(OCC=C)OC

Application

Allyl methyl carbonate, 98% (stabilized with MEHQ) serves as a versatile carbonyl transfer reagent in organic synthesis, enabling efficient protection of alcohols and amines under mild conditions. Its bench-stable nature, enhanced by MEHQ stabilization, facilitates handling and storage while maintaining high reactivity in standard coupling protocols. Functions reliably in nucleophilic substitution cascades and is compatible with diverse functional groups, making it a practical choice for intermediate synthesis in pharmaceutical and agrochemical applications.

Synthesis

  • Route1
    • null|null
      107-18-6
    • null|null
      79-22-1
    • ~93%
    • In-stock
      Ally methyl carbonate,98% (stabilized with MEHQ)|CS-0040098
      35466-83-2

    References

    • Trost, Barry M.; Miller, John R.; Hoffman Jr., Christopher M. Journal of the American Chemical Society, 2011 , vol. 133, # 21 p. 8165 - 8167
  • Route2
    • null|null
      107-18-6
    • null|null
      616-38-6
    • ~80%
    • In-stock
      Ally methyl carbonate,98% (stabilized with MEHQ)|CS-0040098
      35466-83-2

    References

    • Mutlu, Hatice; Ruiz, Johal; Solleder, Susanne C.; Meier, Michael A. R. Green Chemistry, 2012 , vol. 14, # 6 p. 1728 - 1735
  • Route3
    • null|null
      107-18-6
    • null|null
      616-38-6
    • ~%
    • In-stock
      Ally methyl carbonate,98% (stabilized with MEHQ)|CS-0040098
      35466-83-2
    • In-stock
      Diallyl carbonate|CS-0204418
      15022-08-9

    References

    • WO2009/114465 A1, ; Page/Page column 25-26 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Warning
UN#: 3272
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226-H315-H319-H335
Precautionary Statements : P210-P233-P240-P241-P242-P243-P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   35.53
  • LogP   0.9554
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   2

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