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CS-W001157 4
Total: USD 88.00

Allyl ethyl carbonate

  • CAS No. 1469-70-1

  • Cat. No. CS-0197813
  • Purity≥98%
  • MDL No.MFCD00049113

*For research and further manufacturing use only, not for direct human use.

Allyl ethyl carbonate|CS-0197813

Structure of 1469-70-1

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General Information

  • CAS No. 1469-70-1
  • Cat. No. CS-0197813
  • Purity ≥98%
  • MDL No. MFCD00049113
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₆H₁₀O₃
  • Molecular Weight 130.14
  • Synonym(s) Carbonic Acid Allyl Ethyl Ester
  • SMILES C=CCOC(=O)OCC

Description

Allyl ethyl carbonate is a bench-stable, moisture-tolerant reagent featuring a reactive allyl carbonate moiety. This functional group enables efficient coupling reactions under mild conditions, facilitating the introduction of allyl groups into diverse molecular scaffolds with high chemoselectivity and minimal side-product formation.

Application

Allyl ethyl carbonate serves as a versatile protecting group reagent, enabling selective protection of alcohols under mild conditions. Its stability toward a range of reaction environments and facile deprotection with nucleophiles or acid catalysis makes it ideal for multistep synthesis. The allyl moiety allows for orthogonal removal via palladium-catalyzed reactions, enhancing its utility in complex molecule assembly.

Synthesis

  • Route1
    • null|null
      541-41-3
    • null|null
      107-18-6
    • ~92%
    • In-stock
      Allyl ethyl carbonate|CS-0197813
      1469-70-1

    References

    • Loepez, Anna; Moreno-Manas, Marcial; Pleixats, Roser; Roglans, Anna Anales de Quimica, 1997 , vol. 93, # 6 p. 355 - 362
  • Route2
    • null|null
      64-17-5
    • In-stock
      Diallyl carbonate|CS-0204418
      15022-08-9
    • ~%
    • In-stock
      Allyl ethyl carbonate|CS-0197813
      1469-70-1

    References

    • Chemistry - A European Journal, , vol. 18, # 9 p. 2660 - 2665
  • Route3
    • null|null
      2937-50-0
    • ~%
    • null|null
      557-31-3
    • In-stock
      Allyl ethyl carbonate|CS-0197813
      1469-70-1
    • null|null
      107-18-6

    References

    • Bulletin of the Korean Chemical Society, , vol. 33, # 12 p. 4117 - 4121

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Danger
UN#: 3272
Class : 3
Packing Group : Ⅲ
Hazard Statements : H225-H315-H319
Precautionary Statements : P210-P233-P240-P241-P242-P243-P264-P280-P302+P352-P362+P364-P370+P378-P501

Quality Control

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Computational Chemistry Data

  • TPSA   35.53
  • LogP   1.3455
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   3

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