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CS-W001157 4
Total: USD 88.00

Bis((S)-4-(tert-butyl)-4,5-dihydrooxazol-2-yl)methane

  • CAS No. 132098-54-5

  • Cat. No. CS-W010115
  • Purity≥97%
  • MDL No.MFCD00192290

*For research and further manufacturing use only, not for direct human use.

Bis((S)-4-(tert-butyl)-4,5-dihydrooxazol-2-yl)methane|CS-W010115

Structure of 132098-54-5

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General Information

  • CAS No. 132098-54-5
  • Cat. No. CS-W010115
  • Purity ≥97%
  • MDL No. MFCD00192290
  • Storage -20°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₅H₂₆N₂O₂
  • Molecular Weight 266.38
  • Synonym(s) (4S,4'S)-2,2'-methanediylbis(4-tert-butyl-4,5-dihydro-1,3-oxazole)
  • SMILES CC(C)(C)[C@H]1COC(CC2=N[C@@H](C(C)(C)C)CO2)=N1

Description

2,2-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] (BOX ligand) can be used as a C2 symmetric ligand for enantioselective asymmetric catalysis. It easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

Synthesis

  • Route1

    References

    • Denmark, Scott E.; Nakajima, Noriyuki; Stiff, Cory M.; Nicaise, Olivier J.-C.; Kranz, Michael Advanced Synthesis and Catalysis, 2008 , vol. 350, # 7-8 p. 1023 - 1045
  • Route2
    • null|null
      133463-95-3
    • ~42%
    • In-stock
      Bis((S)-4-(tert-butyl)-4,5-dihydrooxazol-2-yl)methane|CS-W010115
      132098-54-5
    • null|null
      133464-00-3

    References

    • Helvetica Chimica Acta, , vol. 74, # 1 p. 232 - 240
  • Route3
    • null|null
      133464-00-3
    • ~%
    • In-stock
      Bis((S)-4-(tert-butyl)-4,5-dihydrooxazol-2-yl)methane|CS-W010115
      132098-54-5

    References

    • Helvetica Chimica Acta, , vol. 74, # 1 p. 232 - 240

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   43.18
  • LogP   3.0633
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   2

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