Methyl 6-chloro-3-fluoropicolinate

Name: Methyl 6-chloro-3-fluoropicolinate
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CAS No. 1030829-21-0
Cat. No. CS-0514277
Purity≥98%
MDL No.MFCD14698146

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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 6-chloro-3-fluoropicolinate|CS-0514277

Structure of 1030829-21-0

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General Information

CAS No. 1030829-21-0
Cat. No. CS-0514277
Purity ≥98%
MDL No. MFCD14698146
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅ClFNO₂
Molecular Weight 189.57
Synonym(s) 6-Chloro-3-fluoro-pyridine-2-carboxylic acid methyl ester
SMILES O=C(C1=NC(Cl)=CC=C1F)OC

Description

Methyl 6-chloro-3-fluoropicolinate features a strategically positioned chloro and fluoro substituent on the picolinate scaffold, enabling enhanced electrophilicity at the carbonyl carbon. This electron-deficient heterocycle integrates readily into transition-metal-catalyzed coupling reactions, offering high functional group tolerance and stability under standard conditions.

Application

Methyl 6-chloro-3-fluoropicolinate serves as a versatile building block in medicinal chemistry, enabling efficient access to fluorinated heterocyclic scaffolds. Its ortho-substituted pyridine core facilitates transition metal-catalyzed cross-coupling reactions, while the methyl ester group supports selective derivatization. The molecule exhibits excellent bench stability and compatibility with diverse functional groups, simplifying purification and integration into multi-step synthetic sequences.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H312-H332
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P363-P501

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Computational Chemistry Data

TPSA 39.19
LogP 1.6607
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Drug Discovery Cancer HPK1

Key Words

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Methyl 6-chloro-3-fluoropicolinate

CAS No. 1030829-21-0

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