(S)-tert-Butyl 3-(methylamino)piperidine-1-carboxylate

Name: (S)-tert-Butyl 3-(methylamino)piperidine-1-carboxylate
Brand: ChemScene
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CAS No. 912368-73-1
Cat. No. CS-0043306
Purity≥95%
MDL No.MFCD09752964

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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(S)-tert-Butyl 3-(methylamino)piperidine-1-carboxylate|CS-0043306

Structure of 912368-73-1

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General Information

CAS No. 912368-73-1
Cat. No. CS-0043306
Purity ≥95%
MDL No. MFCD09752964
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₁H₂₂N₂O₂
Molecular Weight None
Synonym(s) S-N-Boc-3-methylamino piperidine
SMILES O=C(N1C[C@@H](NC)CCC1)OC(C)(C)C

Description

(S)-tert-Butyl 3-(methylamino)piperidine-1-carboxylate features a chiral piperidine core with a methylamino substituent, offering a sterically accessible nitrogen for derivatization. This bench-stable carbamate protects the amine in synthetic sequences while enabling straightforward deprotection under mild acidic conditions. The (S)-configuration ensures stereochemical fidelity in asymmetric synthesis, particularly useful in medicinal chemistry campaigns targeting CNS-active compounds.

Application

(S)-tert-Butyl 3-(methylamino)piperidine-1-carboxylate serves as a versatile chiral building block in medicinal chemistry, enabling the efficient construction of bioactive piperidine scaffolds. Its tert-butyl carbamate group provides excellent bench stability and orthogonal deprotection compatibility, while the N-methylpiperidine moiety offers favorable solubility and metabolic stability. The compound readily participates in standard coupling reactions and functional group interconversions, facilitating rapid diversification in lead optimization campaigns.

Safety Information

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GHS Pictogram :	GHS No : GHS06,GHS09
Signal Word : Danger	UN#: 2810
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H301-H319-H410
Precautionary Statements : P264-P270-P273-P280-P330-P391-P405-P501

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Computational Chemistry Data

TPSA 41.57
LogP 1.6053
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Building Blocks Skeleton Aliphatic heterocycle compounds Piperidine compounds

Key Words

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(S)-tert-Butyl 3-(methylamino)piperidine-1-carboxylate

CAS No. 912368-73-1

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