(2R)-2-Methylmorpholine

Name: (2R)-2-Methylmorpholine
Brand: ChemScene
Availability: InStock
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CAS No. 790184-33-7
Cat. No. CS-0019313
Purity≥96%
MDL No.MFCD11041200

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 790184-33-7

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Description

(2R)-2-Methylmorpholine is a chiral, bench-stable heterocycle featuring a stereogenic center at the 2-position. This configuration imparts distinct spatial orientation to the nitrogen lone pair, enhancing its utility in asymmetric synthesis and as a selective ligand in transition metal catalysis. The molecule’s polar, saturated ring structure enables favorable solubility in common organic solvents while maintaining low nucleophilicity under standard reaction conditions.

Application

(2R)-2-Methylmorpholine serves as a chiral auxiliary and versatile building block in asymmetric synthesis, enabling stereoselective transformations through its well-defined stereochemistry. It functions effectively as a nucleophilic catalyst or ligand in transition-metal-catalyzed reactions, offering enhanced control in C–C and C–heteroatom bond formation. The compound exhibits favorable bench stability, ease of handling, and compatibility with common functional groups, making it a practical choice for iterative synthetic sequences and process-scale applications.

General Information

CAS No. 790184-33-7
Cat. No. CS-0019313
Purity ≥96%
MDL No. MFCD11041200
Storage -20°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₁₁NO
Molecular Weight 101.15
Synonym(s) (2R)-2-Methylmorpholine; (R)-2-Methylmorpholine; Morpholine,2-methyl-, (R)-
SMILES C[C@@H]1CNCCO1

Computational Chemistry Data

TPSA 21.26
LogP -0.0053
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS02,GHS05
Signal Word : Danger	UN#: 2920
Class : 8 (3)	Packing Group : Ⅱ
Hazard Statements : H226-H314-H318
Precautionary Statements : P210-P240-P241-P280-P370+P378

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Other Classifications

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Key Words

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(2R)-2-Methylmorpholine

CAS No. 790184-33-7

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