Lot numbers can be found on the outside label of a product:
(2R)-2-Methylmorpholine
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CAS No. 790184-33-7
- Cat. No. CS-0019313
- Purity≥96%
- MDL No.MFCD11041200
*For research and further manufacturing use only, not for direct human use.
Structure of 790184-33-7
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General Information
- CAS No. 790184-33-7
- Cat. No. CS-0019313
- Purity ≥96%
- MDL No. MFCD11041200
- Storage -20°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₅H₁₁NO
- Molecular Weight 101.15
- Synonym(s) (2R)-2-Methylmorpholine; (R)-2-Methylmorpholine; Morpholine,2-methyl-, (R)-
- SMILES C[C@@H]1CNCCO1
Description
(2R)-2-Methylmorpholine is a chiral, bench-stable heterocycle featuring a stereogenic center at the 2-position. This configuration imparts distinct spatial orientation to the nitrogen lone pair, enhancing its utility in asymmetric synthesis and as a selective ligand in transition metal catalysis. The molecule’s polar, saturated ring structure enables favorable solubility in common organic solvents while maintaining low nucleophilicity under standard reaction conditions.
Application
(2R)-2-Methylmorpholine serves as a chiral auxiliary and versatile building block in asymmetric synthesis, enabling stereoselective transformations through its well-defined stereochemistry. It functions effectively as a nucleophilic catalyst or ligand in transition-metal-catalyzed reactions, offering enhanced control in C–C and C–heteroatom bond formation. The compound exhibits favorable bench stability, ease of handling, and compatibility with common functional groups, making it a practical choice for iterative synthetic sequences and process-scale applications.
Synthesis
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Route1
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914359-99-2 - ~%
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In-stock
790184-33-7
References
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Journal of Organic Chemistry, , vol. 71, # 23 p. 8854 - 8863
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Route2
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914360-11-5
- ~%
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In-stock
790184-33-7
References
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Journal of Organic Chemistry, , vol. 71, # 23 p. 8854 - 8863
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Route3
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914359-85-6
- ~%
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In-stock
790184-33-7
References
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Journal of Organic Chemistry, , vol. 71, # 23 p. 8854 - 8863
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS02,GHS05
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Signal Word : Danger
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UN#: 2920
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Class : 8 (3)
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Packing Group : Ⅱ
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Hazard Statements : H226-H314-H318
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Precautionary Statements : P210-P240-P241-P280-P370+P378
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Quality Control
Computational Chemistry Data
- TPSA 21.26
- LogP -0.0053
- H_Acceptors 2
- H_Donors 1
- Rotatable_Bonds 0
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Key Words
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