(R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-4-oxo-4-(tritylamino)butanoic acid

Name: (R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-4-oxo-4-(tritylamino)butanoic acid
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CAS No. 2044711-09-1
Cat. No. CS-0499135
Purity≥98%
MDL No.None

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(R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-4-oxo-4-(tritylamino)butanoic acid|CS-0499135

Structure of 2044711-09-1

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General Information

CAS No. 2044711-09-1
Cat. No. CS-0499135
Purity ≥98%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₉H₃₄N₂O₅
Molecular Weight 610.70
Synonym(s) (9H-Fluoren-9-yl)MethOxy]Carbonyl N-Me-D-Asn(Trt)-OH
SMILES O=C(OCC1C2=CC=CC=C2C3=CC=CC=C31)N(C)[C@@H](C(O)=O)CC(NC(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)=O

Description

This (R)-configured fluorenylmethoxycarbonyl-protected amino acid derivative features a sterically hindered trityl group and a labile carbamate linkage, enabling efficient incorporation into peptide chains under mild deprotection conditions. The electron-rich fluoren-9-yl moiety facilitates UV detection during synthesis, while the methylamino functionality supports selective coupling reactions. This robust scaffold delivers high-purity peptides with minimal epimerization.

Application

(R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-4-oxo-4-(tritylamino)butanoic acid serves as a robust chiral building block for peptide synthesis, enabling efficient N-terminal protection and side-chain functionalization. The fluorenylmethoxycarbonyl (Fmoc) group ensures orthogonal deprotection under mild basic conditions, while the trityl-protected amine provides steric shielding and enhanced solubility. Its bench-stable nature and compatibility with standard coupling protocols facilitate reliable incorporation into complex peptide scaffolds.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 95.94
LogP 6.8189
H_Acceptors 4
H_Donors 2
Rotatable_Bonds 10

Other Classifications

Building Blocks Functional Group Fmoc

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Chemical Biology Peptide Chemistry Amine Protection

Chemical Biology Peptide Chemistry Unnatural Amino Acid Derivatives

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(R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-4-oxo-4-(tritylamino)butanoic acid

CAS No. 2044711-09-1

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