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Di-μ-chlorobis[2'-(amino-N)[1,1'-biphenyl]-2-yl-C]dipalladium(II)

  • CAS No. 847616-85-7

  • Cat. No. CS-W020950
  • Purity≥95%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

Di-μ-chlorobis[2'-(amino-N)[1,1'-biphenyl]-2-yl-C]dipalladium(II)|CS-W020950

Structure of 847616-85-7

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General Information

  • CAS No. 847616-85-7
  • Cat. No. CS-W020950
  • Purity ≥95%
  • MDL No. None
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₄H₂₀Cl₂N₂Pd₂
  • Molecular Weight 620.18
  • Synonym(s) Di-μ-chlorobis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II)
  • SMILES C12=C(C3=C([NH2][Pd]24Cl[Pd]5(C6=C(C7=C([NH2]5)C=CC=C7)C=CC=C6)Cl4)C=CC=C3)C=CC=C1

Description

This dipalladium(II) complex features two chlorido bridges and biphenyl-based amino ligands, delivering high stability and catalytic efficiency in cross-coupling reactions. The electron-rich aryl framework enhances reactivity, while the μ-chloro bridges facilitate oxidative addition. Ideal for Suzuki-Miyaura coupling under mild conditions.

Application

Di-μ-chlorobis[2'-(amino-N)[1,1'-biphenyl]-2-yl-C]dipalladium(II) serves as a robust, bench-stable precatalyst for cross-coupling reactions, enabling efficient C–C bond formation under mild conditions. Its dual palladium centers and ortho-amino-substituted biphenyl ligand framework enhance catalyst longevity and selectivity in Suzuki-Miyaura and Negishi-type transformations. The complex exhibits excellent functional group tolerance and facilitates scalable synthesis of biaryl scaffolds common in pharmaceutical intermediates.

Safety Information

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GHS Pictogram :
GHS No : GHS02,GHS07,GHS08
Signal Word : Warning
UN#: 3175
Class : 4.1
Packing Group : Ⅱ
Hazard Statements : H225-H228-H302-H315-H319-H335-H336-H351
Precautionary Statements : P210-P240-P241-P261-P264-P271-P280-P302+P352-P305+P351+P338-P362-P370+P378-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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