Bthyl 2-bromo-2-cyclopropylacetate

Name: Bthyl 2-bromo-2-cyclopropylacetate
Brand: ChemScene
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CAS No. 1200828-74-5
Cat. No. CS-0042467
Purity≥97%
MDL No.MFCD18837719

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Bthyl 2-bromo-2-cyclopropylacetate|CS-0042467

Structure of 1200828-74-5

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General Information

CAS No. 1200828-74-5
Cat. No. CS-0042467
Purity ≥97%
MDL No. MFCD18837719
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₁₁BrO₂
Molecular Weight 207.07
Synonym(s) Ethyl 2-bromo-2-cyclopropylacetate
SMILES O=C(OCC)C(Br)C1CC1

Description

Bthyl 2-bromo-2-cyclopropylacetate features a brominated cyclopropyl moiety that enables direct functionalization in synthetic sequences. This bench-stable, moisture-tolerant reagent integrates readily into C–C bond-forming reactions, offering high regioselectivity and compatibility with diverse catalytic systems under standard conditions.

Application

Ethyl 2-bromo-2-cyclopropylacetate serves as a versatile building block for cyclopropyl-containing motifs in medicinal chemistry and natural product synthesis. The α-bromoester functionality enables efficient alkylation, Stille coupling, and transition-metal-catalyzed cross-coupling reactions. Its bench-stable nature and compatibility with diverse functional groups facilitate straightforward purification and integration into complex molecular architectures.

Synthesis

Route1
- 64-17-5
- In-stock
  
  5239-82-7
- ~%
- In-stock
  
  1200828-74-5
References
- WO2013/49250 A1, ; Page/Page column 293; 294 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS05
Signal Word : Danger	UN#: 3265
Class : 8	Packing Group : Ⅲ
Hazard Statements : H314
Precautionary Statements : P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P363-P405-P501

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Computational Chemistry Data

TPSA 26.3
LogP 1.723
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Fatty ring compounds Cyclopropane compounds

Key Words

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Bthyl 2-bromo-2-cyclopropylacetate

CAS No. 1200828-74-5

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