[2,2'-Bipyridine]-6,6'-diamine

Name: [2,2'-Bipyridine]-6,6'-diamine
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 93127-75-4
Cat. No. CS-0085911
Purity≥97%
MDL No.MFCD04117918

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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[2,2'-Bipyridine]-6,6'-diamine|CS-0085911

Structure of 93127-75-4

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General Information

CAS No. 93127-75-4
Cat. No. CS-0085911
Purity ≥97%
MDL No. MFCD04117918
Storage RT, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₀N₄
Molecular Weight None
Synonym(s) 2,2-Bipyridine-6,6-Diamine
SMILES NC1=CC=CC(C2=NC(N)=CC=C2)=N1

Description

6,6'-Diamino-2,2'-bipyridine features a bipyridine core functionalized with amino groups at the 6 and 6' positions, enabling strong chelation with transition metals. This bifunctional scaffold integrates redox-active ligand properties with enhanced solubility and coordination versatility, making it valuable in catalytic systems and coordination polymers.

Application

[2,2'-Bipyridine]-6,6'-diamine serves as a versatile ligand scaffold in transition metal catalysis, enabling efficient coordination to metals such as ruthenium and iron. Its dual pyridyl nitrogen donors and amine functionality offer enhanced solubility and tunable electronic properties, facilitating applications in homogeneous catalysis and redox-active complexes. The molecule exhibits bench stability and compatibility with standard synthetic protocols, supporting scalable synthesis of functionalized bipyridyl architectures.

Synthesis

Route1
- In-stock
  
  49669-22-9
- ~95%
- In-stock
  
  93127-75-4
References
- Thibault, Michelle E.; Luska, Kylie L.; Schlaf, Marcel Synthesis, 2007 , # 5 p. 791 - 793
Route2
- 141341-72-2
- ~84%
- In-stock
  
  93127-75-4
References
- Shimada, Hiroshi; Sakurai, Toshihiko; Kitamura, Yusuke; Matsuura, Hirotaka; Ihara, Toshihiro Dalton Transactions, 2013 , vol. 42, # 45 p. 16006 - 16013
Route3
- In-stock
  
  626-05-1
- ~%
- In-stock
  
  93127-75-4
References
- Synthesis, , # 5 p. 791 - 793

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362+P364

Quality Control

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Computational Chemistry Data

TPSA 77.82
LogP 1.308
H_Acceptors 4
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Bipyridine Ligands

Material Science Material Building Blocks Covalent Organic Frameworks (COFs) Linkers Amine Linkers

Material Science Material Building Blocks Ligands for Functional Metal Complexes Bipyridine Ligands, Terpyridine Ligands

Material Science Polymer/Macromolecule Reagents Covalent Organic Frameworks (COFs) Linkers Amine Linkers

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Amine Ligands

Catalysis Nitrogen-Donor Ligands Bipyridine Ligands, Terpyridine Ligands

Key Words

[2,2'-Bipyridine]-6,6'-diamine sigma[2,2'-Bipyridine]-6,6'-diamine manufacturer[2,2'-Bipyridine]-6,6'-diamine price[2,2'-Bipyridine]-6,6'-diamine structure[2,2'-Bipyridine]-6,6'-diamine SDSbuy [2,2'-Bipyridine]-6,6'-diamine[2,2'-Bipyridine]-6,6'-diamine supplier[2,2'-Bipyridine]-6,6'-diamine uses[2,2'-Bipyridine]-6,6'-diamine molecular weightprice of [2,2'-Bipyridine]-6,6'-diamine[2,2'-Bipyridine]-6,6'-diamine chemical name formula of [2,2'-Bipyridine]-6,6'-diamine

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[2,2'-Bipyridine]-6,6'-diamine

CAS No. 93127-75-4

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