Lot numbers can be found on the outside label of a product:
[2,2'-Bipyridine]-5,5'-diamine
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CAS No. 52382-48-6
- Cat. No. CS-0110285
- Purity≥98%
- MDL No.MFCD14636205
*For research and further manufacturing use only, not for direct human use.
![[2,2'-Bipyridine]-5,5'-diamine|CS-0110285](https://file.chemscene.com/productPIC/CS-0110285.gif)
Structure of 52382-48-6
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General Information
- CAS No. 52382-48-6
- Cat. No. CS-0110285
- Purity ≥98%
- MDL No. MFCD14636205
- Storage 4°C, protect from light
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₀H₁₀N₄
- Molecular Weight 186.21
- Synonym(s) None
- SMILES NC1=CN=C(C=C1)C2=NC=C(C=C2)N
Description
This bipyridine derivative features a diamino substitution at the 5,5′-positions, enhancing its electron-donating character and coordination versatility. The extended conjugation supports robust metal chelation, particularly with transition metals like iron and ruthenium. Its bench-stable nature facilitates use in catalytic systems and redox-active materials without requiring inert atmosphere handling.
Application
[2,2'-Bipyridine]-5,5'-diamine serves as a versatile chelating ligand in transition metal catalysis, enabling efficient coordination to metals such as ruthenium and iron. Its ortho-diamine functionality enhances redox activity and stability in catalytic systems, facilitating applications in cross-coupling and oxidation reactions. The molecule exhibits bench stability, ease of purification, and compatibility with diverse functional groups, making it a practical choice for synthetic workflows requiring robust ligand frameworks.
Synthesis
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Route1
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In-stock
5350-93-6 - ~61%
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In-stock
52382-48-6
References
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Janiak, Christoph; Deblon, Stephan; Wu, He-Ping; Kolm, Mario J.; Kluefers, Peter; Piotrowski, Holger; Mayer, Peter European Journal of Inorganic Chemistry, 1999 , # 9 p. 1507 - 1521
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Route2
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39858-84-9 - ~64%
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In-stock
52382-48-6
References
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Asselin, Catherine M.; Fraser, Greig C.; Hall Jr.; Lindsell, W. Edward; Padias, Anne B.; Preston, Peter N. Journal of the Chemical Society - Dalton Transactions, 1997 , # 20 p. 3765 - 3771
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Route3
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63361-69-3
- ~72%
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In-stock
52382-48-6
References
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Janiak, Christoph; Deblon, Stephan; Wu, He-Ping; Kolm, Mario J.; Kluefers, Peter; Piotrowski, Holger; Mayer, Peter European Journal of Inorganic Chemistry, 1999 , # 9 p. 1507 - 1521
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 77.82
- LogP 1.308
- H_Acceptors 4
- H_Donors 2
- Rotatable_Bonds 1
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Key Words
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