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Di-μ-chlorotetrakis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]diiridium(III)

  • CAS No. 870987-64-7

  • Cat. No. CS-0082944
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

Di-μ-chlorotetrakis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]diiridium(III)|CS-0082944

Structure of 870987-64-7

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General Information

  • CAS No. 870987-64-7
  • Cat. No. CS-0082944
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄₈H₂₀Cl₂F₂₀Ir₂N₄
  • Molecular Weight 1488.01
  • Synonym(s) None
  • SMILES FC1=CC2=C(C3=CC=C(C(F)(F)F)C=[N]3[Ir]45(Cl[Ir]67([N]8=CC(C(F)(F)F)=CC=C8C9=C(F)C=C(F)C=C97)(Cl5)[N]%10=CC(C(F)(F)F)=CC=C%10C%11=C6C=C(F)C=C%11F)2[N]%12=CC(C(F)(F)F)=CC=C%12C%13=C(F)C=C(F)C=C%134)C(F)=C1

Description

Di-μ-chlorotetrakis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]diiridium(III) features a robust dinuclear iridium core bridged by chloride ligands, with each metal center coordinated to sterically hindered, electron-deficient aryl ligands. This complex exhibits enhanced thermal stability and facilitates efficient phosphorescence in OLED applications due to strong spin-orbit coupling and tunable emission via the trifluoromethylpyridine substituents.

Application

Di-μ-chlorotetrakis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]diiridium(III) serves as a robust, air-stable iridium(III) complex that facilitates C–H activation and cyclometalation reactions under mild conditions. Its trifluoromethylated pyridyl ligands enhance electronic modulation and stability, enabling efficient construction of Ir-based photocatalysts and emissive materials. The complex exhibits excellent functional group tolerance and reproducible reactivity in standard synthetic workflows, making it a reliable building block for advanced organometallic applications.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

Quality Control

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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