(2,2'-Bipyridyl)bis[2-(4-tertbutylphenyl) pyridine] iridium (III) hexafluorophosphate

Name: (2,2'-Bipyridyl)bis[2-(4-tertbutylphenyl) pyridine] iridium (III) hexafluorophosphate
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CAS No. 1352428-78-4
Cat. No. CS-0109950
Purity≥97%
MDL No.None

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(2,2'-Bipyridyl)bis[2-(4-tertbutylphenyl) pyridine] iridium (III) hexafluorophosphate|CS-0109950

Structure of 1352428-78-4

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General Information

CAS No. 1352428-78-4
Cat. No. CS-0109950
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₀H₄₀F₆IrN₄P
Molecular Weight 913.95
Synonym(s) ) bis [2- (4-tert-butyL
SMILES CC(C)(C)C1=CC=C(C2=CC=CC=[N]2[Ir+]345([N]6=CC=CC=C6C7=[N]5C=CC=C7)[N]8=CC=CC=C8C9=C4C=C(C(C)(C)C)C=C9)C3=C1.F[P-](F)(F)(F)(F)F

Description

This iridium(III) complex features a bipyridyl-bridged ligand architecture with two 4-tert-butylphenylpyridine units, delivering enhanced stability and efficient phosphorescence. The hexafluorophosphate counterion improves solubility in polar solvents, enabling straightforward integration into OLED devices and solution-processable optoelectronic applications.

Application

(2,2'-Bipyridyl)bis[2-(4-tert-butylphenyl)pyridine] iridium(III) hexafluorophosphate serves as a robust, bench-stable phosphorescent iridium complex widely used in OLED device fabrication. Its structure enables efficient triplet emission through strong spin-orbit coupling, while the bulky 4-tert-butylphenyl substituents enhance solubility and reduce aggregation. The complex functions effectively as a green emitter in multilayered organic light-emitting devices and exhibits favorable stability under operational conditions.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Key Words

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(2,2'-Bipyridyl)bis[2-(4-tertbutylphenyl) pyridine] iridium (III) hexafluorophosphate

CAS No. 1352428-78-4

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