(R)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol

Name: (R)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol
Brand: ChemScene
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CAS No. 851615-07-1
Cat. No. CS-0086802
Purity≥97%
MDL No.None

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(R)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol|CS-0086802

Structure of 851615-07-1

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General Information

CAS No. 851615-07-1
Cat. No. CS-0086802
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₀H₂₆O₂
Molecular Weight 538.63
Synonym(s) None
SMILES OC1=C(C2=C(C=CC=C3)C3=CC(C4=C(C=CC=C5)C5=CC=C4)=C2O)C6=CC=CC=C6C=C1C7=CC=CC8=C7C=CC=C8

Description

This chiral quaternaphthalene diol features a rigid, multi-ring architecture with defined stereochemistry at the 2',2''-positions. The hydroxyl groups enable hydrogen bonding and solubility in polar solvents, while the extended aromatic system supports π-stacking interactions. This structure serves as a robust scaffold for asymmetric synthesis and molecular recognition applications.

Application

(R)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol serves as a chiral building block for the synthesis of complex polycyclic architectures, leveraging its rigid, sterically defined framework to control stereochemistry in asymmetric transformations. The vicinal diol functionality enables selective derivatization and coordination in catalytic systems, while the extended naphthalenic core provides enhanced planarity and π-stacking potential useful in supramolecular and materials chemistry applications.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 40.46
LogP 10.7116
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 3

Key Words

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(R)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol

CAS No. 851615-07-1

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