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CS-W001157 4
Total: USD 88.00

4,4,5,5-Tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane

  • CAS No. 68716-48-3

  • Cat. No. CS-W010221
  • Purity≥97%
  • MDL No.MFCD05663879

*For research and further manufacturing use only, not for direct human use.

4,4,5,5-Tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane|CS-W010221

Structure of 68716-48-3

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General Information

  • CAS No. 68716-48-3
  • Cat. No. CS-W010221
  • Purity ≥97%
  • MDL No. MFCD05663879
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₁₆BNO₄
  • Molecular Weight 249.07
  • Synonym(s) 3-Nitrophenylboronic acid pinacol ester
  • SMILES CC(C(C)(O1)C)(OB1C2=CC([N+]([O-])=O)=CC=C2)C

Synthesis

  • Route1

    References

    • Asachenko, Andrey F.; Sorochkina, Kristina R.; Dzhevakov, Pavel B.; Topchiy, Maxim A.; Nechaev, Mikhail S. Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3553 - 3557
  • Route2
    • null|null
      99-09-2
    • In-stock
      Bis(pinacolato)diborane|CS-D1216
      73183-34-3
    • ~60%
    • In-stock
      4,4,5,5-Tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane|CS-W010221
      68716-48-3

    References

    • Mo, Fanyang; Jiang, Yubo; Qiu, Di; Zhang, Yan; Wang, Jianbo Angewandte Chemie - International Edition, 2010 , vol. 49, # 10 p. 1846 - 1849
  • Route3
    • In-stock
      4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-ol|CS-0176800
      25240-59-9
    • 3-Nitrophenyl trifluoromethanesulfonate|CS-0876208
      32578-25-9
    • ~32%
    • In-stock
      4,4,5,5-Tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane|CS-W010221
      68716-48-3

    References

    • Thompson, Alicia L. S.; Kabalka, George W.; Akula, Murthy R.; Huffman, John W. Synthesis, 2005 , # 4 art. no. M05304SS, p. 547 - 550

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   61.6
  • LogP   1.894
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   2

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