Lot numbers can be found on the outside label of a product:
H-D-Glu(OMe)-OH
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CAS No. 6461-04-7
- Cat. No. CS-W022740
- Purity≥97%
- MDL No.MFCD00237069
*For research and further manufacturing use only, not for direct human use.
Structure of 6461-04-7
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General Information
- CAS No. 6461-04-7
- Cat. No. CS-W022740
- Purity ≥97%
- MDL No. MFCD00237069
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₆H₁₁NO₄
- Molecular Weight 161.16
- Synonym(s) None
- SMILES N[C@@H](C(O)=O)CCC(OC)=O
Description
H-D-Glu(OMe)-OH is a stable, bench-ready D-glutamic acid derivative featuring a methyl ester at the C-terminal carboxyl group. This modification enhances solubility and metabolic stability while preserving the stereochemical integrity essential for peptide synthesis applications.
Application
H-D-Glu(OMe)-OH serves as a stable, bench-ready building block for the synthesis of peptide-based scaffolds and bioactive analogs. The methyl ester group enhances solubility and stability while enabling straightforward hydrolysis under mild conditions. It functions reliably in standard coupling protocols, offering predictable reactivity and compatibility with diverse protecting group strategies in solid-phase and solution-phase synthesis.
Synthesis
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Route1
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In-stock
6893-26-1 -
75-36-5 - ~%
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In-stock
6461-04-7
References
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Tetrahedron, , vol. 56, # 46 p. 9093 - 9102
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Route2
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67-56-1
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In-stock
6893-26-1
- ~%
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In-stock
6461-04-7
References
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Biochemical Preparations, , vol. 5, p. 79,82 Acta Chimica Academiae Scientiarum Hungaricae, , vol. 3, p. 361,364 Tetrahedron, , vol. 2, p. 211,225
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Route3
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5817-08-3 - ~%
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In-stock
6461-04-7
References
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Acta Chimica Academiae Scientiarum Hungaricae, , vol. 3, p. 361,364 Tetrahedron, , vol. 2, p. 211,225
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 89.62
- LogP -0.6485
- H_Acceptors 4
- H_Donors 2
- Rotatable_Bonds 4
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Key Words
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