Lot numbers can be found on the outside label of a product:
Methyl 3-hydroxypicolinate
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CAS No. 62733-99-7
- Cat. No. CS-W022831
- Purity≥98%
- MDL No.MFCD00661311
*For research and further manufacturing use only, not for direct human use.
Structure of 62733-99-7
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General Information
- CAS No. 62733-99-7
- Cat. No. CS-W022831
- Purity ≥98%
- MDL No. MFCD00661311
- Storage Store at room temperature
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₇H₇NO₃
- Molecular Weight 153.14
- Synonym(s) methyl 3-hydroxypyridine-2-carboxylate
- SMILES O=C(C1=NC=CC=C1O)OC
Description
Methyl 3-hydroxypicolinate features a hydroxyl group positioned ortho to the ester functionality, enabling enhanced solubility and reactivity in synthetic transformations. This structural motif facilitates efficient coupling reactions and serves as a key intermediate in the synthesis of bioactive heterocycles and pharmaceutical scaffolds under standard conditions.
Application
Methyl 3-hydroxypicolinate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to pyridine-based scaffolds. The ortho-hydroxy and ester functionalities offer complementary reactivity for selective derivatization, including oxidation to quinones, metal-catalyzed coupling, and protection strategies. Its bench-stable nature and compatibility with standard purification methods make it well-suited for medicinal chemistry campaigns and process development.
Synthesis
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Route1
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67-56-1 -
In-stock
874-24-8 - ~93%
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In-stock
62733-99-7
References
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Wang, Yafei; Deng, Xianping; Liu, Yu; Ni, Meijun; Liu, Ming; Tan, Hua; Li, Xiaoshuang; Zhu, Weiguo; Cao, Yong Tetrahedron, 2011 , vol. 67, # 11 p. 2118 - 2124
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Route2
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In-stock
874-24-8
- ~62%
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In-stock
62733-99-7
References
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Japan Tobacco Inc. Patent: US2003/50320 A1, 2003 ; US 20030050320 A1
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Route3
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36851-80-6
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In-stock
874-24-8
- ~%
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In-stock
62733-99-7
References
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US5294610 A1, ;
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 59.42
- LogP 0.5738
- H_Acceptors 4
- H_Donors 1
- Rotatable_Bonds 1
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