1-Bromo-3-chloro-2-methylbenzene

Name: 1-Bromo-3-chloro-2-methylbenzene
Brand: ChemScene
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CAS No. 62356-27-8
Cat. No. CS-W015365
Purity≥97%
MDL No.MFCD00061121

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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1-Bromo-3-chloro-2-methylbenzene|CS-W015365

Structure of 62356-27-8

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Description

1-Bromo-3-chloro-2-methylbenzene features a methyl group flanked by bromo and chloro substituents on a benzene ring, enabling selective functionalization in cross-coupling reactions. The ortho-bromo substitution provides a reactive handle for palladium-catalyzed transformations, while the meta-chloro group enhances electronic modulation. This regioselective arrangement supports efficient synthesis of complex aromatic scaffolds under standard conditions.

Application

1-Bromo-3-chloro-2-methylbenzene serves as a versatile ortho-disubstituted aryl building block for transition-metal-catalyzed cross-coupling reactions. The bromo group enables efficient Suzuki, Stille, and Negishi couplings, while the chloro and methyl substituents provide regiochemical control and enhanced stability under reaction conditions. This compound facilitates the construction of complex biaryl architectures with predictable substitution patterns, making it a practical choice for medicinal chemistry and materials synthesis workflows.

General Information

CAS No. 62356-27-8
Cat. No. CS-W015365
Purity ≥97%
MDL No. MFCD00061121
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BrCl
Molecular Weight 205.48
Synonym(s) 2-Bromo-6-chlorotoluene
SMILES CC1=C(Cl)C=CC=C1Br

Computational Chemistry Data

TPSA 0
LogP 3.41092
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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1-Bromo-3-chloro-2-methylbenzene

CAS No. 62356-27-8

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