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CS-W001157 4
Total: USD 88.00

N-Iodosuccinimide

  • CAS No. 516-12-1

  • Cat. No. CS-W008878
  • Purity≥97%
  • MDL No.MFCD00005512

*For research and further manufacturing use only, not for direct human use.

N-Iodosuccinimide|CS-W008878

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General Information

  • CAS No. 516-12-1
  • Cat. No. CS-W008878
  • Purity ≥97%
  • MDL No. MFCD00005512
  • Storage 4°C, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄H₄INO₂
  • Molecular Weight 224.98
  • Synonym(s) None
  • SMILES O=C(CC1)N(I)C1=O

Description

Highly substituted iodobenzenes prepared via an efficient 2-step process from 1,6-diynes. Used with TFA to chemoselectively hydrolyze thioglycosides to 1-hydroxyglycosides. Synthesis of vinyl sulfones from olefins and benzenesulfinic acid.

Synthesis

  • Route1

    References

    • Chaikovskii; Skorokhodov; Filimonov Russian Journal of Organic Chemistry, 2001 , vol. 37, # 10 p. 1503 - 1504
  • Route2

    References

    • Poriel, Cyril; Lachia, Mathilde; Wilson, Claire; Davies, James R.; Moody, Christopher J. Journal of Organic Chemistry, 2007 , vol. 72, # 8 p. 2978 - 2987
  • Route3

    References

    • Soundararajan, R.; Krishnamurthy, S.; Srinivasan, Vilanoor S.; Balasubramanian, T.R. Journal of Organometallic Chemistry, 1983 , vol. 255, # 3 p. 295 - 298

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS08,GHS09
Signal Word : Warning
UN#: 3077
Class : 9
Packing Group : Ⅲ
Hazard Statements : H315-H317-H319-H341-H410
Precautionary Statements : P261-P264-P272-P273-P280-P302+P352-P362-P391-P405-P501

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Computational Chemistry Data

  • TPSA   37.38
  • LogP   0.4854
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   0

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