(R)-3-(Benzylthio)-2-((tert-butoxycarbonyl)amino)propanoic acid

Name: (R)-3-(Benzylthio)-2-((tert-butoxycarbonyl)amino)propanoic acid
Brand: ChemScene
Availability: InStock
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CAS No. 5068-28-0
Cat. No. CS-W013957
Purity≥98%
MDL No.MFCD00065567

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(R)-3-(Benzylthio)-2-((tert-butoxycarbonyl)amino)propanoic acid|CS-W013957

Structure of 5068-28-0

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General Information

CAS No. 5068-28-0
Cat. No. CS-W013957
Purity ≥98%
MDL No. MFCD00065567
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₅H₂₁NO₄S
Molecular Weight 311.40
Synonym(s) None
SMILES O=C(O)[C@H](CSCC1=CC=CC=C1)NC(OC(C)(C)C)=O

Description

9-(1-Naphthalenyl)-10-(4-(2-naphthalenyl)phenyl)anthracene (BH) could be used as a blue host in the fabrication of blue OLED device. BH is a host material with a high molecular weight and a great steric hindrance by introducing bulky aromatic rings and rigid cardo structure, and BH have a high thermal stability (Tg of 131 C; Tm of 274 C; and Td of 367 C).With a ET of 1.50 eV, BH is a very popular blue fluorescent host material due to its large band gap (Eg = 3.0 eV).OLED Device Performance1. Ag (100 nm)/TBPDA: TECTFCNBN(97:3,10 nm)/TBPDA (z nm)/BDFTPA (10 nm)/BH: BDFDPPDA (95:5, 20 nm)/NAPIZ: LiQ (50:50, 35 nm)/Yb (1.5 nm)/Ag:Mg = 9:1 (16 nm)/TBPDA (65 nm). Color: blueCIEx,y: (0.1400, 0.0399)Blue index: 139.9Current efficiency: 5.58 Cd/A2. ITO/HATCN (5 nm)/DBPTPPB(100 nm)/TPN-DBF (10 nm)/BH:BTBF-DPh = 25:1 (40 nm)/ANT-BIZ (40 nm)/Liq (2.5 nm)/Al (100 nm)Color: blueCIEx,y: (0.151, 0.069)Max. CE: 2.96 Cd/AMax. EQE: 4.23 %3. ITO (150 nm)/HAT-CN (10 nm)/TBPDIA (60 nm)/DFBDDbA (10 nm)/BH:BD (5 wt%) (25 nm)/NAPI:LiQ = 1:1 (35 nm)/Al (80 nm).Color: blueCIEx,y: (0.1288, 0.1581)Lifetime: 277 h at 10 mA cm-2Max. EQE: 7.15 %Max. CE: 8.52 Cd/A4. ITO/HATCN (5 nm)/LHT001 (30 nm)/LEB001 (5 nm)/BD (10%):BH (20 nm)/LET003 (30 nm)/Liq (2 nm)/Al and nondoped structure ITO/HATCN (5 nm)/NPB (50 nm)/BD (20 nm)/LET003 (30 nm)/Liq (2 nm)/AlColor: blueCIEx,y: (0.16, 0.06)Max. EQE: 4.01 %Max. CE: 3.09 Cd/AMax. PE: 2.56 Cd/AEL FWHM: 51 nm

Synthesis

Route1
- In-stock
  
  3054-01-1
- In-stock
  
  24424-99-5
- ~99%
- In-stock
  
  5068-28-0
References
- Koerber-Ple; Massiot Journal of Heterocyclic Chemistry, 1995 , vol. 32, # 4 p. 1309 - 1315
Route2
- 100-39-0
- ~%
- In-stock
  
  5068-28-0
References
- Koerber-Ple; Massiot Journal of Heterocyclic Chemistry, 1995 , vol. 32, # 4 p. 1309 - 1315
Route3
- In-stock
  
  3054-01-1
- In-stock
  
  13303-10-1
- ~%
- In-stock
  
  5068-28-0
References
- Anderson; McGregor Journal of the American Chemical Society, 1957 , vol. 79, p. 6180,6181

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 75.63
LogP 2.8977
H_Acceptors 4
H_Donors 2
Rotatable_Bonds 6

Other Classifications

Bioactive Molecules Peptides

Life Science Amino Acids and their Derivatives Cysteine and derivatives

Chemical Biology Peptide Chemistry Amine Protection

Chemical Biology Peptide Chemistry Unnatural Amino Acid Derivatives

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(R)-3-(Benzylthio)-2-((tert-butoxycarbonyl)amino)propanoic acid

CAS No. 5068-28-0

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