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CS-W001157 4
Total: USD 88.00

(3AR,5S,5aR,8aS,8bR)-5-(iodomethyl)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran

  • CAS No. 4026-28-2

  • Cat. No. CS-0452274
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(3AR,5S,5aR,8aS,8bR)-5-(iodomethyl)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452274

Structure of 4026-28-2

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General Information

  • CAS No. 4026-28-2
  • Cat. No. CS-0452274
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, sealed storage, away from moisture and light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₁₉IO₅
  • Molecular Weight 370.18
  • Synonym(s) 6-Deoxy-1,2:3,4-di-O-isopropylidene-6-iodo-ALPHA-D-galactopyranose
  • SMILES CC1(C)O[C@H]2[C@@H](CI)O[C@H]3[C@@H]([C@H]2O1)OC(C)(C)O3

Synthesis

  • Route1
    • ((3AR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran-5-yl)methyl 4-methylbenzenesulfonate|CS-0468334
      4478-43-7
    • ~%
    • In-stock
      (3AR,5S,5aR,8aS,8bR)-5-(iodomethyl)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452274
      4026-28-2

    References

    • Foster et al. Journal of the Chemical Society, 1949 , p. 2542,2545 Full Text Show Details Raymond; Schroeder Journal of the American Chemical Society, 1948 , vol. 70, p. 2785,2790 Full Text Show Details Freudenberg; Raschig Chemische Berichte, 1927 , vol. 60, p. 1633 Chemische Berichte, 1929 , vol. 62, p. 373
  • Route2
    • null|null
      80667-80-7
    • null|null
      74-88-4
    • ~76%
    • In-stock
      (3AR,5S,5aR,8aS,8bR)-5-(iodomethyl)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452274
      4026-28-2

    References

    • Vatele, Jean-Michel; Hanessian, Stephen Tetrahedron, 1996 , vol. 52, # 32 p. 10557 - 10568
  • Route3
    • ((3AR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran-5-yl)methyl 4-methylbenzenesulfonate|CS-0468334
      4478-43-7
    • ~12%
    • In-stock
      (3AR,5S,5aR,8aS,8bR)-5-(iodomethyl)-2,2,7,7-tetramethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452274
      4026-28-2
    • null|null
      155480-30-1
    • In-stock
      1,2:3,4-Di-O-isopropylidene-α-D-galactopyranose|CS-0091624
      4064-06-6

    References

    • Mootoo, David; Wilson, Phyllis; Jammalamadaka, Vasu Journal of Carbohydrate Chemistry, 1994 , vol. 13, # 6 p. 841 - 850

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319
Precautionary Statements : P264-P270-P280-P302+P352-P330-P362+P364-P501

Quality Control

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Computational Chemistry Data

  • TPSA   46.15
  • LogP   1.8179
  • H_Acceptors   5
  • H_Donors   0
  • Rotatable_Bonds   1

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