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CS-W001157 4
Total: USD 88.00

(3AR,5R,5aS,8aS,8bR)-2,2,5,7,7-pentamethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran

  • CAS No. 4026-27-1

  • Cat. No. CS-0452273
  • Molecule weight244.28
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(3AR,5R,5aS,8aS,8bR)-2,2,5,7,7-pentamethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452273

Structure of 4026-27-1

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General Information

  • CAS No. 4026-27-1
  • Cat. No. CS-0452273
  • Purity ≥98%
  • MDL No. None
  • Storage Sealed in dry,2-8℃
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₂₀O₅
  • Molecular Weight 244.28
  • Synonym(s) 1,2,3,4-DI-O-ISOPROPYLIDENE-ALPHA-D-FUCOSE
  • SMILES C[C@@H]1[C@H]2[C@@H]([C@@H]3[C@H](O1)OC(C)(C)O3)OC(C)(C)O2

Synthesis

  • Route1
    • null|null
      53867-05-3
    • ~94%
    • (3AR,5R,5aS,8aS,8bR)-2,2,5,7,7-pentamethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452273
      4026-27-1

    References

    • Odedra, Arjan; Geyer, Karolin; Gustafsson, Tomas; Gilmour, Ryan; Seeberger, Peter H. Chemical Communications, 2008 , # 26 p. 3025 - 3027
  • Route2
    • null|null
      16714-07-1
    • ~92%
    • (3AR,5R,5aS,8aS,8bR)-2,2,5,7,7-pentamethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452273
      4026-27-1

    References

    • Benati, Luisa; Leardini, Rino; Minozzi, Matteo; Nanni, Daniele; Scialpi, Rosanna; Spagnolo, Piero; Strazzari, Samantha; Zanardi, Giuseppe Angewandte Chemie - International Edition, 2004 , vol. 43, # 27 p. 3598 - 3601
  • Route3
    • null|null
      1424273-58-4
    • ~75%
    • (3AR,5R,5aS,8aS,8bR)-2,2,5,7,7-pentamethyltetrahydro-5H-bis([1,3]dioxolo)[4,5-b:4',5'-d]pyran|CS-0452273
      4026-27-1

    References

    • Kobayashi, Shoji; Kuroda, Hiroyuki; Ohtsuka, Yuta; Kashihara, Takashi; Masuyama, Araki; Watanabe, Kiyoshi Tetrahedron, 2013 , vol. 69, # 10 p. 2251 - 2259

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   46.15
  • LogP   1.4028
  • H_Acceptors   5
  • H_Donors   0
  • Rotatable_Bonds   0

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