(2,3-Dichlorophenyl)methanamine

Name: (2,3-Dichlorophenyl)methanamine
Brand: ChemScene
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CAS No. 39226-95-4
Cat. No. CS-W017423
Purity≥95%
MDL No.MFCD00047927

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(2,3-Dichlorophenyl)methanamine|CS-W017423

Structure of 39226-95-4

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General Information

CAS No. 39226-95-4
Cat. No. CS-W017423
Purity ≥95%
MDL No. MFCD00047927
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇Cl₂N
Molecular Weight 176.04
Synonym(s) 2,3-Dichlorobenzylamine
SMILES NCC1=CC=CC(Cl)=C1Cl

Description

(2,3-Dichlorophenyl)methanamine is a chlorinated aromatic amine featuring two chlorine atoms in the ortho and meta positions relative to the methylene-amino group. This electron-deficient scaffold offers enhanced reactivity in nucleophilic substitution reactions and serves as a key building block for pharmaceutical intermediates. The molecule exhibits good stability under standard bench conditions and facilitates efficient coupling in transition-metal-catalyzed transformations.

Application

(2,3-Dichlorophenyl)methanamine serves as a versatile building block in medicinal chemistry, enabling the synthesis of bioactive heterocycles and pharmaceutical intermediates. Its dichlorinated aromatic core provides enhanced metabolic stability and favorable lipophilicity for drug discovery applications. The primary amine group facilitates straightforward functionalization via coupling reactions, reductive amination, or acylation, offering robust access to diverse compound libraries with high purity and bench stability.

Synthesis

Route1
- In-stock
  
  6574-97-6
- ~77%
- In-stock
  
  39226-95-4
References
- Journal of Organic Chemistry, , vol. 77, # 1 p. 221 - 228
Route2
- 32768-54-0
- ~%
- In-stock
  
  39226-95-4
References
- Journal of the Chemical Society, , p. 1414 - 1416

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS05
Signal Word : Danger	UN#: 2735
Class : 8	Packing Group : Ⅲ
Hazard Statements : H314
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 26.02
LogP 2.4521
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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(2,3-Dichlorophenyl)methanamine

CAS No. 39226-95-4

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