Boc-Gly-OMe

Name: Boc-Gly-OMe
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 31954-27-5
Cat. No. CS-W022602
Purity≥98%
MDL No.MFCD00038267

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Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 31954-27-5

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General Information

CAS No. 31954-27-5
Cat. No. CS-W022602
Purity ≥98%
MDL No. MFCD00038267
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₁₅NO₄
Molecular Weight 189.21
Synonym(s) None
SMILES O=C(OC)CNC(OC(C)(C)C)=O

Description

Boc-Gly-OMe serves as a protected glycine derivative for peptide synthesis, featuring a tert-butoxycarbonyl (Boc) group at the N-terminus and a methyl ester at the C-terminus. This dual protection enables stable coupling under standard conditions while simplifying deprotection workflows.

Application

Boc-Gly-OMe serves as a reliable building block for peptide synthesis, offering enhanced stability and ease of handling. The Boc group provides orthogonal protection for the amine, while the methyl ester facilitates efficient coupling reactions. Its bench-stable nature and compatibility with standard deprotection protocols make it well-suited for iterative solid-phase and solution-phase peptide assembly.

Synthesis

Route1
- 57218-61-8
- 75-65-0
- ~95%
- In-stock
  
  31954-27-5
References
- Okumoto, Hiroshi; Nishihara, Satoshi; Yamamoto, Sinya; Hino, Hirokazu; Nozawa, Akihiro; Suzuki, Akira Synlett, 2000 , # 7 p. 991 - 992
Route2
- 67-56-1
- In-stock
  
  4530-20-5
- ~96%
- In-stock
  
  31954-27-5
References
- TOKUYAMA CORPORATION Patent: EP1178043 A1, 2002 ; Location in patent: Page 31, 32 ;
Route3
- In-stock
  
  4530-20-5
- In-stock
  
  61985-23-7
- ~92%
- In-stock
  
  31954-27-5
References
- Heller, Stephen T.; Sarpong, Richmond Organic Letters, 2010 , vol. 12, # 20 p. 4572 - 4575

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 64.63
LogP 0.6841
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Bioactive Molecules Peptides

Life Science Amino Acids and their Derivatives Glycine and derivatives

Life Science Amino Acids and their Derivatives C-protected amino acid

Chemical Biology Peptide Chemistry Amine Protection

Chemical Biology Peptide Chemistry Amino Acid Derivatives

Chemical Biology Pharmaceutical Development and Drug Discovery Research Reagents Peptide Chemistry Amino Acid Derivatives

Chemical Biology Pharmaceutical Development and Drug Discovery Research Peptide Chemistry Amino Acid Derivatives

Biochemistry Biochemicals and Reagents Amino Acids C-ProtectedAmino Acids

Biochemistry Biochemicals and Reagents Amino Acids N-Protected Amino Acids

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Boc-Gly-OMe

CAS No. 31954-27-5

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