Lot numbers can be found on the outside label of a product:
1,1,1-Tris(diphenylphosphino)methane
-
CAS No. 28926-65-0
- Cat. No. CS-0108404
- Purity≥95%
- MDL No.MFCD00015527
*For research and further manufacturing use only, not for direct human use.
Structure of 28926-65-0
Please choose your location and provide accurate information for you
| Size |
|
Price | Quantity | |||
|---|---|---|---|---|---|---|
|
* Please select Quantity before adding items. |
||||||
Recommended Products
General Information
- CAS No. 28926-65-0
- Cat. No. CS-0108404
- Purity ≥95%
- MDL No. MFCD00015527
- Storage 4°C, protect from light, stored under nitrogen
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₃₇H₃₁P₃
- Molecular Weight 568.58
- Synonym(s) None
- SMILES C(P(C1=CC=CC=C1)C2=CC=CC=C2)(P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6
Description
1,1,1-Tris(diphenylphosphino)methane is a sterically crowded phosphine ligand featuring three diphenylphosphino groups attached to a central methylene carbon. This triphosphine motif delivers strong electron donation and enhanced stability in transition metal complexes. The molecule's rigid, three-dimensional architecture facilitates precise control over coordination geometry in catalytic systems. It is particularly effective in palladium- and nickel-catalyzed cross-coupling reactions, where its robustness under reaction conditions improves catalyst longevity and turnover efficiency.
Application
1,1,1-Tris(diphenylphosphino)methane serves as a versatile, bench-stable tridentate phosphine ligand in transition metal catalysis. Its three diphenylphosphino groups enable strong coordination to palladium, platinum, and rhodium centers, facilitating efficient cross-coupling reactions, hydrogenation processes, and C–H activation. The ligand’s steric bulk and electron-donating properties enhance catalyst stability and turnover, particularly in challenging transformations. Its high solubility and ease of purification make it well-suited for both academic research and industrial process development.
Synthesis
-
Route1
-
28926-61-6 -
1079-66-9
- ~54%
-
In-stock
28926-65-0
References
-
Schmidbaur, Hubert; Stuetzer, Albert; Herdtweck, Eberhardt Chemische Berichte, 1991 , vol. 124, # 5 p. 1095 - 1100
-
-
Route2
-
In-stock
2071-20-7 - ~%
-
In-stock
28926-65-0
References
-
Schmidbaur, Hubert; Stuetzer, Albert; Herdtweck, Eberhardt Chemische Berichte, 1991 , vol. 124, # 5 p. 1095 - 1100
-
-
Route3
-
1079-66-9
-
In-stock
2071-20-7
- ~%
-
In-stock
28926-65-0
References
-
Appel,R. et al. Chemische Berichte, 1979 , vol. 112, p. 1093 - 1095
-
Safety Information
Download SDS|
GHS Pictogram :
|
GHS No : GHS07
|
|
Signal Word : Warning
|
UN#: N/A
|
|
Class : N/A
|
Packing Group : N/A
|
|
Hazard Statements : H315-H319-H335
|
|
|
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
|
|
Quality Control
Computational Chemistry Data
- TPSA 0
- LogP 7.6687
- H_Acceptors 0
- H_Donors 0
- Rotatable_Bonds 9
Similar Products
Recently Viewed Products
Leave US a Message
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Upload Pictures
|
|
Key Words
- 1,1,1-Tris(diphenylphosphino)methane sigma1,1,1-Tris(diphenylphosphino)methane manufacturer1,1,1-Tris(diphenylphosphino)methane price1,1,1-Tris(diphenylphosphino)methane structure1,1,1-Tris(diphenylphosphino)methane SDSbuy 1,1,1-Tris(diphenylphosphino)methane1,1,1-Tris(diphenylphosphino)methane supplier1,1,1-Tris(diphenylphosphino)methane uses1,1,1-Tris(diphenylphosphino)methane molecular weightprice of 1,1,1-Tris(diphenylphosphino)methane1,1,1-Tris(diphenylphosphino)methane chemical name formula of 1,1,1-Tris(diphenylphosphino)methane