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CS-W001157 4
Total: USD 88.00

(E)-1,2-Bis(diphenylphosphanyl)ethene

  • CAS No. 983-81-3

  • Cat. No. CS-0067164
  • Molecule weight396.40
  • Purity≥97%
  • MDL No.MFCD00063219

*For research and further manufacturing use only, not for direct human use.

(E)-1,2-Bis(diphenylphosphanyl)ethene|CS-0067164

Structure of 983-81-3

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General Information

  • CAS No. 983-81-3
  • Cat. No. CS-0067164
  • Purity ≥97%
  • MDL No. MFCD00063219
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₆H₂₂P₂
  • Molecular Weight 396.40
  • Synonym(s) trans-Vinylenebis(diphenylphosphine)
  • SMILES P(/C=C/P(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Description

Catalyst for:Coupling of primary and secondary alkyl halides with aryl grignard reagentsHomogeneous hydrogenation of Carbon Dioxide mediated by RutheniumReactant for:Preparation of cyclopalladated derivatives of benzylidenePreparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agentsCatalytic asymetric intramolecular hydroamination of alkynylamines

Synthesis

  • Route1
    • null|null
      156-60-5
    • null|null
      829-85-6
    • ~88%
    • In-stock
      (E)-1,2-Bis(diphenylphosphanyl)ethene|CS-0067164
      983-81-3

    References

    • Shulyupin, Mstilsav O.; Chirkov, Evgeniy A.; Kazankova, Marina A.; Beletskaya, Irina P. Synlett, 2005 , # 4 art. no. G46004ST, p. 658 - 660
  • Route2
    • null|null
      156-60-5
    • null|null
      1079-66-9
    • ~81%
    • In-stock
      (E)-1,2-Bis(diphenylphosphanyl)ethene|CS-0067164
      983-81-3

    References

    • Brunner, Henri; Muschiol, Manfred; Zabel, Manfred Synthesis, 2008 , # 3 p. 405 - 408
  • Route3
    • null|null
      829-85-6
    • In-stock
      Bis(diphenylphosphino)acetylene|CS-0086022
      5112-95-8
    • ~0%
    • null|null
      113088-15-6
    • null|null
      113088-16-7
    • In-stock
      (E)-1,2-Bis(diphenylphosphanyl)ethene|CS-0067164
      983-81-3

    References

    • Schmidbaur, Hubert; Paschalidis, Christos; Reber, Gabriele; Mueller, Gerhard Chemische Berichte, 1988 , vol. 121, p. 1241 - 1246

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   5.7234
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   6

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