Methyl 3-bromo-2-methoxybenzoate

Name: Methyl 3-bromo-2-methoxybenzoate
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 260806-90-4
Cat. No. CS-0041494
Purity≥97%
MDL No.MFCD11042778

HazMat Fee +

HazMat Fee

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

The shipment is processed through FedEx Ground under the Limited Quantity option.

Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Methyl 3-bromo-2-methoxybenzoate|CS-0041494

Structure of 260806-90-4

Size

Price

Quantity

* Please select Quantity before adding items.

General Information

CAS No. 260806-90-4
Cat. No. CS-0041494
Purity ≥97%
MDL No. MFCD11042778
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₉BrO₃
Molecular Weight 245.07
Synonym(s) Benzoic acid, 3-bromo-2-methoxy-, methyl ester
SMILES COC(=O)C1=C(OC)C(Br)=CC=C1

Description

Methyl 3-bromo-2-methoxybenzoate features a bromine atom at the meta position relative to the ester, paired with a methoxy group ortho to the carbonyl. This electron-deficient aromatic scaffold enables direct functionalization in cross-coupling reactions and serves as a key intermediate in synthesizing bioactive heterocycles and pharmaceuticals under standard conditions.

Application

Methyl 3-bromo-2-methoxybenzoate serves as a versatile building block for Suzuki-Miyaura and Stille coupling reactions, enabling the construction of biaryl and heteroaryl scaffolds under standard conditions. The bromine atom exhibits high reactivity in palladium-catalyzed cross-couplings, while the methoxy and ester groups provide orthogonal functionality for further derivatization. Its bench-stable nature and ease of purification make it well-suited for iterative synthesis workflows in medicinal chemistry and process development.

Synthesis

Route1
- 67-56-1
- In-stock
  
  101084-39-3
- ~97%
- In-stock
  
  260806-90-4
References
- Kline; Bowman; Iglewski; De Kievit; Kakai; Passador Bioorganic and Medicinal Chemistry Letters, 1999 , vol. 9, # 24 p. 3447 - 3452
Route2
- In-stock
  
  3883-95-2
- 77-78-1
- ~%
- In-stock
  
  260806-90-4
References
- Laatsch, Hartmut; Pudleiner, Heinz Liebigs Annalen der Chemie, 1989 , p. 863 - 882

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Computational Chemistry Data

TPSA 35.53
LogP 2.2443
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

Methyl 3-bromo-2-methoxybenzoate sigmaMethyl 3-bromo-2-methoxybenzoate manufacturerMethyl 3-bromo-2-methoxybenzoate priceMethyl 3-bromo-2-methoxybenzoate structureMethyl 3-bromo-2-methoxybenzoate SDSbuy Methyl 3-bromo-2-methoxybenzoateMethyl 3-bromo-2-methoxybenzoate supplierMethyl 3-bromo-2-methoxybenzoate usesMethyl 3-bromo-2-methoxybenzoate molecular weightprice of Methyl 3-bromo-2-methoxybenzoateMethyl 3-bromo-2-methoxybenzoate chemical name formula of Methyl 3-bromo-2-methoxybenzoate

Salutation:	*Country or Region:
*Applicant Name:	*Organization Name:
*Email Address:	Quantity:
CAS NO. :	Product Name:
Remarks:
Upload Pictures

CAS.No.		Product Name
Applicant Name *		Email Address *
Phone Number *		Organization Name*
Country or Region*		Quantity*
Remarks:

Product Name:
Cat. No.: .		CAS NO. :
Quantity:

Methyl 3-bromo-2-methoxybenzoate

CAS No. 260806-90-4

Recommended Products