Dimethyl L-glutamate hydrochloride

Name: Dimethyl L-glutamate hydrochloride
Brand: ChemScene
Availability: InStock
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CAS No. 23150-65-4
Cat. No. CS-W020521
Purity≥95%
MDL No.MFCD00038879

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Dimethyl L-glutamate hydrochloride|CS-W020521

Structure of 23150-65-4

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General Information

CAS No. 23150-65-4
Cat. No. CS-W020521
Purity ≥95%
MDL No. MFCD00038879
Storage 4°C, sealed storage, away from moisture
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₁₄ClNO₄
Molecular Weight 211.64
Synonym(s) Dimethyl glutamate (hydrochloride)
SMILES N[C@@H](CCC(OC)=O)C(OC)=O.Cl

Description

Glutamic acid dimethyl ester hydrochloride features a fully methylated carboxylate moiety, enhancing solubility and stability in aqueous and organic media. This derivative simplifies purification workflows and serves as a robust precursor in peptide synthesis and bioconjugation applications.

Application

Glutamic acid dimethyl ester hydrochloride serves as a versatile diester building block for peptide synthesis and heterocyclic chemistry. Its well-defined carboxylate functionality enables selective derivatization, while the protonated amine enhances solubility and facilitates purification. The dimethyl ester groups are stable under standard bench conditions and can be selectively cleaved or transformed in established protocols, making it a practical choice for synthetic intermediates in medicinal chemistry and process development.

Synthesis

Route1
- 67-56-1
- In-stock
  
  56-86-0
- ~10%
- In-stock
  
  23150-65-4
References
- Geiger, Christian; Zelenka, Christel; Weigl, Manuela; Froehlich, Roland; Wibbeling, Birgit; Lehmkuhl, Kirstin; Schepmann, Dirk; Gruenert, Renate; Bednarski, Patrick J.; Wuensch, Bernhard Journal of Medicinal Chemistry, 2007 , vol. 50, # 24 p. 6144 - 6153
Route2
- 75-77-4
- In-stock
  
  56-86-0
- ~99%
- In-stock
  
  23150-65-4
References
- Weigl, Manuela; Wuensch, Bernhard Tetrahedron, 2002 , vol. 58, # 6 p. 1173 - 1183
Route3
- 129421-88-1
- ~16%
- 16052-64-5
- In-stock
  
  23150-65-4
References
- Liebigs Annalen der Chemie, , # 11 p. 1115 - 1118

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 78.62
LogP -0.1383
H_Acceptors 5
H_Donors 1
Rotatable_Bonds 4

Other Classifications

Bioactive Molecules Peptides

Life Science Amino Acids and their Derivatives Glutamic acid and derivatives

Life Science Amino Acids and their Derivatives C-protected amino acid

Chemical Biology Peptide Chemistry Amino Acid Derivatives

Chemical Biology Pharmaceutical Development and Drug Discovery Research Reagents Peptide Chemistry Amino Acid Derivatives

Chemical Biology Pharmaceutical Development and Drug Discovery Research Peptide Chemistry Amino Acid Derivatives

Biochemistry Biochemicals and Reagents Amino Acids C-ProtectedAmino Acids

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Dimethyl L-glutamate hydrochloride

CAS No. 23150-65-4

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