(+)-Diisopropyl L-tartrate

Name: (+)-Diisopropyl L-tartrate
Brand: ChemScene
Availability: InStock
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CAS No. 2217-15-4
Cat. No. CS-0010100
Molecule weight234.25
Purity≥95%
MDL No.MFCD00064450

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 2217-15-4

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General Information

CAS No. 2217-15-4
Cat. No. CS-0010100
Purity ≥95%
MDL No. MFCD00064450
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₈O₆
Molecular Weight 234.25
Synonym(s) (+)-DIPT; L-(+)-Tartaric Acid Diisopropyl Ester
SMILES O=C(OC(C)C)[C@H](O)[C@@H](O)C(OC(C)C)=O

Description

(+)-Diisopropyl L-tartrate serves as a chiral auxiliary in asymmetric synthesis, enabling stereocontrolled transformations through its well-defined stereogenic centers. This bench-stable diester integrates readily into enantioselective reactions, delivering predictable stereochemical outcomes under standard conditions.

Application

(+)-Diisopropyl L-tartrate serves as a well-established chiral auxiliary in asymmetric synthesis, enabling stereoselective transformations through its defined stereochemistry. It functions effectively in enantioselective additions and epoxidations, offering high diastereoselectivity and bench stability. The compound's ease of purification and compatibility with standard reaction conditions make it a reliable choice for the construction of chiral building blocks in medicinal chemistry and natural product synthesis.

Synthesis

Route1
- 87-91-2
- 67-63-0
- ~84%
- In-stock
  
  2217-15-4
References
- Ranu, Brindaban C.; Dutta, Pinak; Sarkar, Arunkanti Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 6027 - 6028
Route2
- 1061180-99-1
- In-stock
  
  18680-27-8
- ~0%
- In-stock
  
  2217-15-4
- 76110-78-6
References
- Roy, Chandra D.; Brown, Herbert C. Monatshefte fur Chemie, 2007 , vol. 138, # 9 p. 879 - 887
Route3
- 1061180-99-1
- In-stock
  
  504-63-2
- ~0%
- In-stock
  
  4406-77-3
- In-stock
  
  2217-15-4
References
- Roy, Chandra D.; Brown, Herbert C. Monatshefte fur Chemie, 2007 , vol. 138, # 9 p. 879 - 887

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 93.06
LogP -0.3886
H_Acceptors 6
H_Donors 2
Rotatable_Bonds 5

Other Classifications

Building Blocks Functional Group Alcohol

Building Blocks Functional Group Ester

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Building Blocks Skeleton Chiral compounds Chiral Resolution Reagent

Building Blocks Skeleton Fatty chain compounds

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Epoxidation

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(+)-Diisopropyl L-tartrate

CAS No. 2217-15-4

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