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CS-W001157 4
Total: USD 88.00

L-(+)-Tartaric acid dimethyl ester

  • CAS No. 608-68-4

  • Cat. No. CS-0093793
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

L-(+)-Tartaric acid dimethyl ester|CS-0093793

Structure of 608-68-4

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General Information

  • CAS No. 608-68-4
  • Cat. No. CS-0093793
  • Purity ≥98%
  • MDL No. None
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₆H₁₀O₆
  • Molecular Weight 178.14
  • Synonym(s) L-plus-tartaric acid dimethyl ester; L-(+)-Tartaric acid dimethyl ester
  • SMILES O=C([C@H](O)[C@@H](O)C(OC)=O)OC

Description

(+)-Dimethyl L-tartrate can react with sulfur tetrafluoride to form dimethyl meso-2,3-difluorosuccinate.It may be used in the synthesis of the following chiral ligands for use in asymmetric synthesis:(2R, 3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol(-)-(4S,5R)-4-(2-pyridyl)-5-(diphenylphosphino)methyl-2,2-dimethyl-1,3-dioxolane (PYDIPHOS)(4R,5R)-,,,-2,2-hexaphenyl-4,5-dimethanol-1,3-dioxolane

Synthesis

  • Route1
    • Dimethyl (2R,3R,5R,6R)-5,6-dimethoxy-1,4-dioxane-2,3-dicarboxylate|CS-0097541
      181586-74-3
    • ~80%
    • In-stock
      L-(+)-Tartaric acid dimethyl ester|CS-0093793
      608-68-4

    References

    • Tzschucke, C. Christoph; Pradidphol, Narathip; Dieguez-Vazquez, Alejandro; Kongkathip, Boonsong; Kongkathip, Ngampong; Ley, Steven V. Synlett, 2008 , # 9 p. 1293 - 1296
  • Route2
    • null|null
      87-69-4
    • null|null
      149-73-5
    • ~97%
    • In-stock
      L-(+)-Tartaric acid dimethyl ester|CS-0093793
      608-68-4

    References

    • Meier, Bettina; Kollroser, Manfred; Presser, Armin Monatshefte fur Chemie, 2014 , vol. 145, # 2 p. 305 - 309
  • Route3
    • null|null
      67-56-1
    • null|null
      87-69-4
    • ~85%
    • In-stock
      L-(+)-Tartaric acid dimethyl ester|CS-0093793
      608-68-4

    References

    • Ram, Ram N.; Charles Tetrahedron, 1997 , vol. 53, # 21 p. 7335 - 7340

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   93.06
  • LogP   -1.9458
  • H_Acceptors   6
  • H_Donors   2
  • Rotatable_Bonds   3

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