(Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt

Name: (Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt
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CAS No. 201870-82-8
Cat. No. CS-0855633
Purity≥97%
MDL No.None

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(Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt|CS-0855633

Structure of 201870-82-8

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General Information

CAS No. 201870-82-8
Cat. No. CS-0855633
Purity ≥97%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₈H₅₅CoN₂O₄
Molecular Weight 662.79
Synonym(s) None
SMILES CC([O-][Co+3]123[N]([C@@]4([H])[C@](CCCC4)([H])[N]2=CC5=CC(C(C)(C)C)=CC(C(C)(C)C)=C5[O-]3)=CC6=CC(C(C)(C)C)=CC(C(C)(C)C)=C6[O-]1)=O

Description

This cobalt complex features a sterically shielded, electron-rich ligand framework derived from a bulky bisphenol scaffold with nitrile and acetate donors. The coordinated cobalt center resides in a rigid, multidentate environment that enhances stability and modulates redox behavior, enabling controlled catalytic activity under ambient conditions.

Application

This cobalt complex serves as a robust catalyst for C–H functionalization and oxidative coupling reactions, leveraging its stable tridentate ligand framework. The sterically shielded phenolate donors enhance redox stability and selectivity, while the acetato bridge facilitates reversible coordination. Its bench-stable nature and tolerance to diverse functional groups enable reliable use in multistep syntheses and heterocycle construction.

Safety Information

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GHS Pictogram :	GHS No : GHS07,GHS08
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H351
Precautionary Statements : P264-P280-P302+P352-P305+P351+P338-P362+P364-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

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(Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt

CAS No. 201870-82-8

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