Methyl 2-amino-5-methylbenzoate

Name: Methyl 2-amino-5-methylbenzoate
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CAS No. 18595-16-9
Cat. No. CS-W002654
Purity≥98%
MDL No.MFCD00661547

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 2-amino-5-methylbenzoate|CS-W002654

Structure of 18595-16-9

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General Information

CAS No. 18595-16-9
Cat. No. CS-W002654
Purity ≥98%
MDL No. MFCD00661547
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₁₁NO₂
Molecular Weight 165.19
Synonym(s) Methyl 6-Amino-m-toluate
SMILES COC(=O)c1cc(C)ccc1N

Application

Methyl 2-amino-5-methylbenzoate serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient access to substituted benzimidazoles and other heterocyclic scaffolds. Its ortho-amino and methyl groups facilitate directed metallation and electrophilic substitution, while the ester functionality supports orthogonal transformations. Bench-stable and readily purified by recrystallization, it functions effectively in standard coupling and cyclization protocols.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 52.32
LogP 1.36382
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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Methyl 2-amino-5-methylbenzoate

CAS No. 18595-16-9

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