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CS-W001157 4
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4'-Methyl[2,2'-bipyridine]-4-butanoic acid

  • CAS No. 114527-28-5

  • Cat. No. CS-0085507
  • Purity≥95%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

4'-Methyl[2,2'-bipyridine]-4-butanoic acid|CS-0085507

Structure of 114527-28-5

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General Information

  • CAS No. 114527-28-5
  • Cat. No. CS-0085507
  • Purity ≥95%
  • MDL No. None
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₅H₁₆N₂O₂
  • Molecular Weight 256.30
  • Synonym(s) 4-(4'-Methyl-[2,2'-bipyridin]-4-yl)butanoic acid
  • SMILES CC1=CC(C2=NC=CC(CCCC(O)=O)=C2)=NC=C1

Description

4'-Methyl[2,2'-bipyridine]-4-butanoic acid features a methyl-substituted bipyridine core paired with a butanoic acid side chain, enabling coordination to metal centers while enhancing solubility and modulating electronic properties. This structure facilitates integration into supramolecular architectures and catalytic systems under standard conditions.

Application

4'-Methyl[2,2'-bipyridine]-4-butanoic acid serves as a versatile ligand building block for transition metal catalysis and coordination chemistry. The conjugated bipyridine core provides strong chelation to metals such as ruthenium and iron, while the pendant butanoic acid functional group enables facile derivatization via amide or ester formation. Bench-stable and compatible with standard coupling reactions, it facilitates the construction of functionalized polypyridyl scaffolds relevant to photocatalytic systems and molecular materials.

Synthesis

  • Route1
    • null|null
      115008-01-0
    • ~50%
    • In-stock
      4'-Methyl[2,2'-bipyridine]-4-butanoic acid|CS-0085507
      114527-28-5

    References

    • Ciana, Leopoldo Della; Hamachi, Itaru; Meyer, Thomas J. Journal of Organic Chemistry, 1989 , vol. 54, # 7 p. 1731 - 1735
  • Route2

    References

    • Ciana, Leopoldo Della; Hamachi, Itaru; Meyer, Thomas J. Journal of Organic Chemistry, 1989 , vol. 54, # 7 p. 1731 - 1735
  • Route3
    • null|null
      114527-27-4
    • ~73%
    • In-stock
      4'-Methyl[2,2'-bipyridine]-4-butanoic acid|CS-0085507
      114527-28-5

    References

    • Nussbaumer, W.; Gruber, H.; Greber, G. F. Monatshefte fuer Chemie, 1988 , vol. 119, p. 1 - 16

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   63.08
  • LogP   2.85932
  • H_Acceptors   3
  • H_Donors   1
  • Rotatable_Bonds   5

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