(3-Chloro-4-hydroxyphenyl)boronic acid

Name: (3-Chloro-4-hydroxyphenyl)boronic acid
Brand: ChemScene
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CAS No. 182344-13-4
Cat. No. CS-W005080
Purity≥98%
MDL No.MFCD09258739

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(3-Chloro-4-hydroxyphenyl)boronic acid|CS-W005080

Structure of 182344-13-4

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General Information

CAS No. 182344-13-4
Cat. No. CS-W005080
Purity ≥98%
MDL No. MFCD09258739
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₆BClO₃
Molecular Weight 172.37
Synonym(s) boronic acid, B-(3-chloro-4-hydroxyphenyl)-
SMILES OC1=CC=C(B(O)O)C=C1Cl

Description

This boronic acid features a chlorinated hydroxyphenyl scaffold enabling direct functionalization in cross-coupling reactions. The ortho-hydroxyl group enhances solubility and facilitates chelation, while the chlorine substituent provides a handle for further derivatization. Bench-stable under standard conditions, it integrates efficiently into complex molecule synthesis workflows.

Application

(3-Chloro-4-hydroxyphenyl)boronic acid serves as a versatile building block in Suzuki-Miyaura cross-coupling reactions, enabling efficient construction of biaryl scaffolds with high functional group tolerance. The ortho-chloro and phenolic hydroxyl groups provide strategic handles for further derivatization, while the boronic acid moiety offers excellent bench stability and ease of purification. This compound functions reliably in both solution-phase and solid-phase synthesis workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 60.69
LogP -0.2746
H_Acceptors 3
H_Donors 3
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Boronic Acid And Its Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Chemical Synthesis Organometallic Reagents Organoboron Boronic Acids and Derivatives

Key Words

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(3-Chloro-4-hydroxyphenyl)boronic acid

CAS No. 182344-13-4

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