(t-Bu)PhCPhos

Name: (t-Bu)PhCPhos
Brand: ChemScene
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CAS No. 1660153-91-2
Cat. No. CS-0088286
Purity≥97%
MDL No.MFCD29905429

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 1660153-91-2
Cat. No. CS-0088286
Purity ≥97%
MDL No. MFCD29905429
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₆H₃₃N₂P
Molecular Weight 404.53
Synonym(s) 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl; 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl (t-Bu)PhCPhos
SMILES CN(C)C1=CC=CC(N(C)C)=C1C2=C(P(C3=CC=CC=C3)C(C)(C)C)C=CC=C2

Application

(t-Bu)PhCPhos serves as a highly effective, bench-stable phosphine ligand in palladium-catalyzed cross-coupling reactions. Its bulky tert-butyl and phenyl substituents enhance catalyst longevity and promote efficient reductive elimination, enabling reliable coupling of challenging substrates such as aryl chlorides and sterically hindered partners. The ligand exhibits broad functional group tolerance and simplifies purification due to minimal byproduct formation, making it well-suited for scalable synthesis and high-throughput screening workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H413
Precautionary Statements : P264-P273-P280-P302+P352-P362+P364-P501

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Computational Chemistry Data

TPSA 6.48
LogP 5.7168
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 5

Key Words

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(t-Bu)PhCPhos

CAS No. 1660153-91-2

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