(2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate

Name: (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
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CAS No. 1580547-45-0
Cat. No. CS-0109948
Purity≥98%
MDL No.None

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(2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate|CS-0109948

Structure of 1580547-45-0

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General Information

CAS No. 1580547-45-0
Cat. No. CS-0109948
Purity ≥98%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₂H₂₂F₈IrN₄P
Molecular Weight 837.73
Synonym(s) (Ir[p-Fppy]2(bpy))PF6
SMILES FC1=CC=C(C2=CC=CC=[N]2[Ir+]345([N]6=CC=CC=C6C7=[N]5C=CC=C7)[N]8=CC=CC=C8C9=C4C=C(F)C=C9)C3=C1.F[P-](F)(F)(F)(F)F

Description

This iridium(III) complex features a bipyridyl-bridged architecture with two 2-(4-fluorophenyl)pyridine ligands, delivering enhanced charge transport and photoluminescent stability. The hexafluorophosphate counterion improves solubility in polar media, enabling efficient integration into solution-processed OLED devices.

Application

This iridium(III) complex serves as a highly efficient phosphorescent emitter in organic light-emitting devices. The bipyridyl and pyridine ligands provide strong chelation, enhancing thermal and photochemical stability. Its fluorinated aryl groups improve electron affinity and facilitate charge transport, while the hexafluorophosphate counterion supports solution processability. Functions reliably in standard device architectures, enabling high quantum efficiency and color purity in emissive layers.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

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(2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate

CAS No. 1580547-45-0

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