Lot numbers can be found on the outside label of a product:
Fmoc-Glu-OMe
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CAS No. 145038-49-9
- Cat. No. CS-W022728
- Purity≥95%
- MDL No.MFCD21607506
*For research and further manufacturing use only, not for direct human use.
Structure of 145038-49-9
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General Information
- CAS No. 145038-49-9
- Cat. No. CS-W022728
- Purity ≥95%
- MDL No. MFCD21607506
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₂₁H₂₁NO₆
- Molecular Weight 383.40
- Synonym(s) None
- SMILES O=C(O)CC[C@H](NC(OCC1C2=C(C3=C1C=CC=C3)C=CC=C2)=O)C(OC)=O
Description
Fmoc-Glu-OMe features a protected glutamic acid side chain with a methyl ester, enabling direct incorporation into peptide chains without additional derivatization. The Fmoc group ensures efficient orthogonal deprotection during solid-phase synthesis, while the methyl ester maintains stability under standard coupling conditions. This derivative simplifies sequence assembly in bioactive peptide synthesis.
Application
Fmoc-Glu-OMe serves as a key building block in solid-phase peptide synthesis, enabling efficient incorporation of glutamic acid residues with orthogonal protection. The Fmoc group permits base-labile deprotection, while the methyl ester provides a stable, easily removable carboxyl handle. Its bench-stable nature and compatibility with standard coupling protocols facilitate reliable peptide chain elongation and simplify purification workflows.
Synthesis
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Route1
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160002-61-9 - ~%
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In-stock
145038-49-9
References
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Tamiaki, Hitoshi; Isoda, Yasuaki; Tanaka, Takuya; Machida, Shinnosuke Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 4 p. 1421 - 1428
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References
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Dumez, Estelle; Snaith, John S.; Jackson, Richard F. W.; McElroy, Andrew B.; Overington, John; Wythes, Martin J.; Withka, Jane M.; McLellan, Thomas J. Journal of Organic Chemistry, 2002 , vol. 67, # 14 p. 4882 - 4892
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Route3
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In-stock
71989-18-9 - ~%
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In-stock
145038-49-9
References
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Walker, Brian; Brown, Martin F.; Lynas, John F.; Martin; McDowell, Andrew; Badet, Bernard; Hill, Alan J. Bioorganic and Medicinal Chemistry Letters, 2000 , vol. 10, # 24 p. 2795 - 2798
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 101.93
- LogP 2.9315
- H_Acceptors 5
- H_Donors 2
- Rotatable_Bonds 7
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Key Words
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