(5-Bromo-2-methylpyridin-3-yl)methanol

Name: (5-Bromo-2-methylpyridin-3-yl)methanol
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CAS No. 1346541-53-4
Cat. No. CS-0053163
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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(5-Bromo-2-methylpyridin-3-yl)methanol|CS-0053163

Structure of 1346541-53-4

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General Information

CAS No. 1346541-53-4
Cat. No. CS-0053163
Purity ≥98%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈BrNO
Molecular Weight 202.05
Synonym(s) 5-Bromo-3-(hydroxymethyl)-2-methylpyridine
SMILES CC1=NC=C(Br)C=C1CO

Description

(5-Bromo-2-methylpyridin-3-yl)methanol features a pyridine core bearing bromo and methyl substituents at meta and ortho positions relative to the methanol group, delivering enhanced electrophilicity and stability. This bench-stable reagent integrates readily into cross-coupling and functionalization workflows, enabling efficient access to complex heterocyclic architectures in medicinal chemistry and materials synthesis.

Application

(5-Bromo-2-methylpyridin-3-yl)methanol serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient late-stage functionalization via Suzuki-Miyaura and Buchwald-Hartwig coupling reactions. The pendant alcohol group facilitates derivatization through etherification or oxidation to the aldehyde, while the bromo and methyl substituents offer orthogonal reactivity for sequential transformations. Bench-stable and amenable to purification by flash chromatography, it functions reliably in multi-step syntheses requiring regioselective heterocycle functionalization.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H312-H332
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P501

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Computational Chemistry Data

TPSA 33.12
LogP 1.64482
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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(5-Bromo-2-methylpyridin-3-yl)methanol

CAS No. 1346541-53-4

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