Methyl 5-bromo-6-hydroxy-2-methylpyridine-3-carboxylate

Name: Methyl 5-bromo-6-hydroxy-2-methylpyridine-3-carboxylate
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CAS No. 1334499-25-0
Cat. No. CS-0239219
Molecule weight246.06
Purity≥95%
MDL No.MFCD20232419

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Methyl 5-bromo-6-hydroxy-2-methylpyridine-3-carboxylate|CS-0239219

Structure of 1334499-25-0

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General Information

CAS No. 1334499-25-0
Cat. No. CS-0239219
Purity ≥95%
MDL No. MFCD20232419
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO₃
Molecular Weight 246.06
Synonym(s) Methyl 5-bromo-2-methyl-6-oxo-1,6-dihydrop yridine-3-carboxylate
SMILES CC1=NC(=C(C=C1C(=O)OC)Br)O

Description

Methyl 5-bromo-6-hydroxy-2-methylpyridine-3-carboxylate features a brominated pyridine core with orthogonal functional groups enabling direct derivatization. The hydroxy and ester moieties offer strategic handles for cross-coupling, cyclization, or bioconjugation under mild conditions. This bench-stable intermediate supports rapid access to substituted heterocycles in medicinal chemistry and agrochemical synthesis.

Application

Methyl 5-bromo-6-hydroxy-2-methylpyridine-3-carboxylate serves as a versatile building block for pyridine-based heterocycles, enabling direct functionalization at C5 and C6 positions. The bromo group facilitates palladium-catalyzed cross-coupling reactions, while the hydroxyl function supports derivatization or protection strategies. Bench-stable and compatible with standard synthetic workflows, it functions effectively in the construction of medicinally relevant scaffolds through orthogonal reactivity.

Safety Information

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Signal Word : N/A	UN#: N/A
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Computational Chemistry Data

TPSA 59.42
LogP 1.64472
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 5-bromo-6-hydroxy-2-methylpyridine-3-carboxylate

CAS No. 1334499-25-0

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