Methyl 4-bromo-2-formylbenzoate

Name: Methyl 4-bromo-2-formylbenzoate
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CAS No. 1260795-42-3
Cat. No. CS-0101120
Purity≥98%
MDL No.MFCD16036574

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 4-bromo-2-formylbenzoate|CS-0101120

Structure of 1260795-42-3

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General Information

CAS No. 1260795-42-3
Cat. No. CS-0101120
Purity ≥98%
MDL No. MFCD16036574
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₇BrO₃
Molecular Weight 243.05
Synonym(s) None
SMILES O=C(C1=CC=C(C=C1C=O)Br)OC

Description

Methyl 4-bromo-2-formylbenzoate features a formyl group ortho to a methyl ester and para to a bromine, enabling direct functionalization in cross-coupling or nucleophilic addition reactions. This electron-deficient aromatic scaffold integrates readily into complex molecular architectures under standard conditions.

Application

Methyl 4-bromo-2-formylbenzoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted benzimidazoles and other heterocyclic scaffolds. The molecule combines a bromo group for cross-coupling reactions and a formyl function for nucleophilic addition or condensation processes. Its bench-stable nature and compatibility with standard reaction conditions facilitate straightforward purification and integration into multi-step syntheses.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 43.37
LogP 2.0482
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 4-bromo-2-formylbenzoate

CAS No. 1260795-42-3

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