Methyl 6-chloro-4-methylpicolinate

Name: Methyl 6-chloro-4-methylpicolinate
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CAS No. 1186605-87-7
Cat. No. CS-0105057
Purity≥97%
MDL No.None

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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 6-chloro-4-methylpicolinate|CS-0105057

Structure of 1186605-87-7

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General Information

CAS No. 1186605-87-7
Cat. No. CS-0105057
Purity ≥97%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈ClNO₂
Molecular Weight 185.61
Synonym(s) methyl 6-chloro-4-methyl-pyridine-2-carboxylate
SMILES O=C(C1=NC(Cl)=CC(C)=C1)OC

Description

Methyl 6-chloro-4-methylpicolinate is a bench-stable, moisture-tolerant heterocyclic ester featuring a chlorine atom at the 6-position and a methyl group at the 4-position of the picolinate core. This electronic profile enables selective coupling in cross-coupling reactions, facilitating efficient access to substituted pyridine derivatives under standard conditions.

Application

Methyl 6-chloro-4-methylpicolinate serves as a versatile building block in medicinal chemistry, enabling efficient access to substituted pyridine scaffolds. Its ortho-chloro and methyl groups provide complementary sites for cross-coupling reactions and electrophilic functionalization. The ester functionality facilitates downstream transformations, including hydrolysis and amide formation, while the molecule exhibits excellent bench stability and compatibility with standard synthetic protocols.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 1.83002
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

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Methyl 6-chloro-4-methylpicolinate

CAS No. 1186605-87-7

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