2,6-Dichloro-4-methylbenzaldehyde

Name: 2,6-Dichloro-4-methylbenzaldehyde
Brand: ChemScene
Availability: InStock
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CAS No. 116070-31-6
Cat. No. CS-0061252
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2,6-Dichloro-4-methylbenzaldehyde|CS-0061252

Structure of 116070-31-6

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General Information

CAS No. 116070-31-6
Cat. No. CS-0061252
Purity ≥95%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₆Cl₂O
Molecular Weight 189.04
Synonym(s) None
SMILES CC1=CC(=C(C=O)C(=C1)Cl)Cl

Description

2,6-Dichloro-4-methylbenzaldehyde features a sterically hindered aromatic core with electron-withdrawing chlorine atoms at the 2 and 6 positions, enhancing stability and directing electrophilic substitution. The para-methyl group provides steric and electronic modulation, while the aldehyde functionality enables direct coupling in cross-coupling reactions and condensation chemistry under standard conditions.

Application

2,6-Dichloro-4-methylbenzaldehyde serves as a valuable building block in medicinal chemistry and agrochemical synthesis, offering enhanced electrophilicity at the carbonyl group due to electron-withdrawing chlorine substituents. Its ortho-chloro substitution provides steric protection and improves bench stability, while the methyl group enables further functionalization via oxidation or directed metallation. The compound facilitates efficient construction of substituted benzimidazoles, heterocyclic scaffolds, and arylated intermediates under standard coupling conditions.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 17.07
LogP 3.11432
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Aldehyde

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2,6-Dichloro-4-methylbenzaldehyde

CAS No. 116070-31-6

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