Lot numbers can be found on the outside label of a product:
Methyl 2-(diethoxyphosphoryl)acetate
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CAS No. 1067-74-9
- Cat. No. CS-W019238
- Purity≥98%
- MDL No.MFCD00009081
*For research and further manufacturing use only, not for direct human use.
Structure of 1067-74-9
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General Information
- CAS No. 1067-74-9
- Cat. No. CS-W019238
- Purity ≥98%
- MDL No. MFCD00009081
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₇H₁₅O₅P
- Molecular Weight 210.17
- Synonym(s) None
- SMILES O=C(OC)CP(OCC)(OCC)=O
Description
Reactant or reagent for: Synthesis of branches allylic fluoridesRegioselective Diels-Alder reactions to yield antibiotic building blocksSubstituted thiophenes and furans synthesis for treatment of type 2 diabetesStereoselective Diels-Alder cycloaddition reactionsSynthesis of pyridone alkaloids with neuritogenic activityModification of botulinum neurotoxin serotype A protease inhibitorsSynthesis of immunosuppressive cyclopentanediol derivatives
Application
Methyl diethylphosphonoacetate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to phosphonate-containing compounds via well-established Horner-Wadsworth-Emmons and related olefination reactions. Its stable, bench-friendly nature and compatibility with diverse functional groups facilitate straightforward purification and scalable synthesis. Functions effectively in the construction of α,β-unsaturated carbonyl systems and heterocyclic scaffolds relevant to medicinal chemistry and agrochemical development.
Synthesis
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Route1
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96-34-4 -
122-52-1
- ~99%
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In-stock
1067-74-9
References
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Aung, Hnin Thanda; Furukawa, Tadashi; Nikai, Toshiaki; Niwa, Masatake; Takaya, Yoshiaki Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 7 p. 2392 - 2396
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Route2
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96-32-2
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122-52-1
- ~99%
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In-stock
1067-74-9
References
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Davies, Stephen G.; Fletcher, Ai M.; Roberts, Paul M.; Smith, Andrew D. Tetrahedron, 2009 , vol. 65, # 49 p. 10192 - 10213
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Route3
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67-56-1
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In-stock
867-13-0 - ~10%
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In-stock
1067-74-9
References
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Remme, Nicole; Koschek, Katharina; Schneider, Christoph Synlett, 2007 , # 3 p. 491 - 493
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H315-H319
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Precautionary Statements : P264-P280-P302+P352-P362
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Quality Control
Computational Chemistry Data
- TPSA 61.83
- LogP 1.4255
- H_Acceptors 5
- H_Donors 0
- Rotatable_Bonds 6
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