5-Bromo-2-methylisonicotinaldehyde

Name: 5-Bromo-2-methylisonicotinaldehyde
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CAS No. 1060810-15-2
Cat. No. CS-0102724
Purity≥97%
MDL No.MFCD13189311

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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5-Bromo-2-methylisonicotinaldehyde|CS-0102724

Structure of 1060810-15-2

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General Information

CAS No. 1060810-15-2
Cat. No. CS-0102724
Purity ≥97%
MDL No. MFCD13189311
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BrNO
Molecular Weight 200.03
Synonym(s) 5-bromo-2-methylpyridine-4-carbaldehyde
SMILES O=CC1=CC(C)=NC=C1Br

Description

5-Bromo-2-methylisonicotinaldehyde features a bromine atom at the 5-position and a methyl group at the 2-position of the isonicotinaldehyde scaffold, delivering enhanced electron deficiency and steric profile. This configuration enables efficient coupling in cross-coupling reactions and facilitates incorporation into bioactive heterocycles. The aldehyde functionality provides direct handle for conjugation under mild conditions.

Application

5-Bromo-2-methylisonicotinaldehyde serves as a versatile building block in medicinal chemistry and heterocyclic synthesis, enabling efficient access to substituted pyridine derivatives via cross-coupling and condensation reactions. Its brominated pyridine core supports palladium-catalyzed transformations, while the aldehyde functionality facilitates imine formation and reductive amination. The methyl group enhances metabolic stability and provides a handle for further functionalization. Bench-stable and readily purified by distillation or chromatography, it functions reliably in multistep syntheses requiring orthogonal reactivity.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 29.96
LogP 1.96502
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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5-Bromo-2-methylisonicotinaldehyde

CAS No. 1060810-15-2

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