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CS-W001157 4
Total: USD 88.00

(4-Bromophenyl)(methyl)sulfane

  • CAS No. 104-95-0

  • Cat. No. CS-W015471
  • Purity≥98%
  • MDL No.MFCD00000102

*For research and further manufacturing use only, not for direct human use.

(4-Bromophenyl)(methyl)sulfane|CS-W015471

Structure of 104-95-0

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General Information

  • CAS No. 104-95-0
  • Cat. No. CS-W015471
  • Purity ≥98%
  • MDL No. MFCD00000102
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₇BrS
  • Molecular Weight None
  • Synonym(s) 4-Bromothioanisole
  • SMILES CSC1=CC=C(Br)C=C1

Description

4-Bromothioanisole undergoes Heck olefination reaction with styrenes to yield stilbenes.4-Bromothioanisole was used in the synthesis of:4-nitro-4-mercaptobiphenyl4-iodo-4-mercaptobiphenyl3-nitro-4-mercaptobiphenyl3-iodo-4-mercaptiobiphenyl(S)-()-p-bromophenyl methyl sulfoxide

Synthesis

  • Route1

    References

    • Zhang, Guangyou; Lv, Guanglei; Li, Liping; Chen, Fan; Cheng, Jiang Tetrahedron Letters, 2011 , vol. 52, # 16 p. 1993 - 1995
  • Route2

    References

    • Bauld, Nathan L.; Aplin, J. Todd; Yueh, Wang; Loinaz, Ainhoa Journal of the American Chemical Society, 1997 , vol. 119, # 47 p. 11381 - 11389
  • Route3

    References

    • Oh, Kyungsoo; Knabe, William Eric Tetrahedron, 2009 , vol. 65, # 15 p. 2966 - 2974

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: 3335
Class : 9
Packing Group : Ⅲ
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.171
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   1

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