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CS-W001157 4
Total: USD 88.00

1-Bromo-3,5-dimethylbenzene

  • CAS No. 556-96-7

  • Cat. No. CS-W016968
  • Purity≥98%
  • MDL No.MFCD00000087

*For research and further manufacturing use only, not for direct human use.

1-Bromo-3,5-dimethylbenzene|CS-W016968

Structure of 556-96-7

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General Information

  • CAS No. 556-96-7
  • Cat. No. CS-W016968
  • Purity ≥98%
  • MDL No. MFCD00000087
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₉Br
  • Molecular Weight 185.06
  • Synonym(s) 5-Bromo-m-xylene
  • SMILES CC1=CC(Br)=CC(C)=C1

Description

Palladium catalyzed carbon-oxygen coupling of 1-bromo-3,5-dimethylbenzene and o-cresol to potassium hydroxide to produce o-tolyl-3,5-xylyl ether has been reported.1-Bromo-3,5-dimethylbenzene has been used in the synthesis of substituted 2,2-bis(diphenylphosphanylmethyl)-1,1-binaphthyl derivatives.

Synthesis

  • Route1

    References

    • Zhang, Guangyou; Lv, Guanglei; Li, Liping; Chen, Fan; Cheng, Jiang Tetrahedron Letters, 2011 , vol. 52, # 16 p. 1993 - 1995
  • Route2
    • null|null
      108-69-0
    • ~89%
    • In-stock
      1-Bromo-3,5-dimethylbenzene|CS-W016968
      556-96-7

    References

    • Lee, Jong Gun; Cha, Hee Tae Tetrahedron Letters, 1992 , vol. 33, # 22 p. 3167 - 3168
  • Route3

    References

    • Journal of the American Chemical Society, , vol. 124, # 50 p. 14844 - 14845

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H227-H315-H319
Precautionary Statements : P210-P264-P280-P302+P352-P362-P370+P378-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.06594
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   0

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