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CS-W001157 4
Total: USD 88.00

(R)-Tol-BINAP

  • CAS No. 99646-28-3

  • Cat. No. CS-0015957
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(R)-Tol-BINAP|CS-0015957

Structure of 99646-28-3

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General Information

  • CAS No. 99646-28-3
  • Cat. No. CS-0015957
  • Purity ≥97%
  • MDL No. None
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄₈H₄₀P₂
  • Molecular Weight 678.78
  • Synonym(s) (R)-2,2'-Bis(di-4-tolylphosphino)-1,1'-binaphthyl; (R)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl; (R)-2,2'-Bis[bis(4-tolyl)phosphino]-1,1'-binaphthyl; (R)-p-tolyl-BINAP; (R)-(+)-TolBINAP; (R)-Tol-BINAP
  • SMILES C=1C=CC=2C(C1)=CC=C(C2C=3C=4C=CC=CC4C=CC3P(C5=CC=C(C=C5)C)C6=CC=C(C=C6)C)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C

Synthesis

  • Route1
    • null|null
      100165-87-5
    • ~94%
    • In-stock
      (R)-Tol-BINAP|CS-0015957
      99646-28-3

    References

    • Wu, Hai-Chen; Yu, Jin-Quan; Spencer, Jonathan B. Organic Letters, 2004 , vol. 6, # 25 p. 4675 - 4678
  • Route2
    • null|null
      1342819-36-6
    • In-stock
      (S)-[1,1'-Binaphthalene]-2,2'-diyl bis(trifluoromethanesulfonate)|CS-0031304
      128544-05-8
    • ~66%
    • In-stock
      (R)-Tol-BINAP|CS-0015957
      99646-28-3

    References

    • Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
  • Route3
    • Chlorodi-p-tolylphosphane|CS-0182673
      1019-71-2
    • In-stock
      (S)-[1,1'-Binaphthalene]-2,2'-diyl bis(trifluoromethanesulfonate)|CS-0031304
      128544-05-8
    • ~45%
    • In-stock
      (R)-Tol-BINAP|CS-0015957
      99646-28-3

    References

    • Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   8.80764
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   5

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