Lot numbers can be found on the outside label of a product:
6,6'-Bis(bromomethyl)-2,2'-bipyridine
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CAS No. 96517-97-4
- Cat. No. CS-0203068
- Purity≥95%
- MDL No.MFCD27920801
*For research and further manufacturing use only, not for direct human use.
Structure of 96517-97-4
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General Information
- CAS No. 96517-97-4
- Cat. No. CS-0203068
- Purity ≥95%
- MDL No. MFCD27920801
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₂H₁₀Br₂N₂
- Molecular Weight 342.03
- Synonym(s) None
- SMILES BrCC1=NC(=CC=C1)C=2N=C(C=CC2)CBr
Description
6,6'-Bis(bromomethyl)-2,2'-bipyridine features two bromomethyl groups flanking the bipyridine core, enabling facile functionalization in ligand design. This bifunctional scaffold integrates readily into coordination complexes and modular synthetic sequences, offering precise control over metal binding geometry and electronic tuning.
Application
6,6'-Bis(bromomethyl)-2,2'-bipyridine serves as a versatile bifunctional building block for the construction of chelating ligands and coordination polymers. The bromomethyl groups enable efficient post-functionalization via nucleophilic substitution, facilitating the attachment of diverse side chains or incorporation into larger molecular architectures. Its stability under standard bench conditions and compatibility with common coupling reactions make it a practical choice for synthesizing tailored ligands in catalysis and materials science applications.
Synthesis
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Route1
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In-stock
4411-80-7 - ~51%
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In-stock
96517-97-4
References
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Zhao, Shuang; Ito, Shintaro; Ohba, Yoshihiro; Katagiri, Hiroshi Tetrahedron Letters, 2014 , vol. 55, # 13 p. 2097 - 2100
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Route2
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In-stock
4411-80-7
- ~55%
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96517-98-5 -
In-stock
96517-97-4
References
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Wang, Zheng; Reibenspies, Joseph; Motekaitis, Ramunas J.; Martell, Arthur E. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1995 , # 9 p. 1511 - 1518
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Route3
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In-stock
1824-81-3 - ~%
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In-stock
96517-97-4
References
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Maheswari, Palanisamy Uma; Lappalainen, Kristian; Sfregola, Michael; Barends, Sharief; Gamez, Patrick; Turpeinen, Urho; Mutikainen, Ilpo; Van Wezel, Gilles P.; Reedijk, Jan Dalton Transactions, 2007 , # 33 p. 3676 - 3683
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS05
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Signal Word : Danger
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UN#: 3261
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Class : 8
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Packing Group : Ⅲ
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Hazard Statements : H290-H314
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Precautionary Statements : P234-P260-P264-P280-P301+P330+P331-P304+P340-P363-P390-P405-P406-P501
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Quality Control
Computational Chemistry Data
- TPSA 25.78
- LogP 3.9334
- H_Acceptors 2
- H_Donors 0
- Rotatable_Bonds 3
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Key Words
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